Electron spin

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Gabi_Maldonado_1B
Posts: 95
Joined: Fri Sep 24, 2021 7:33 am

Electron spin

Postby Gabi_Maldonado_1B » Wed Oct 20, 2021 10:42 pm

When filling the p,d, and f orbitals with electrons, is it correct to put electrons in each orbital with parallel spins, before pairing the electrons in orbitals and reversing the spin of the second one?

Xuan Lai 1H
Posts: 100
Joined: Fri Sep 24, 2021 5:13 am
Been upvoted: 4 times

Re: Electron spin

Postby Xuan Lai 1H » Wed Oct 20, 2021 10:46 pm

Yes this is correct. Hund's rule states that orbitals of the same energy must first be occupied singly (parallel spins) before doubly occupied, and when that is the case, then the electrons have opposite spins.

Eszter Kovacs 1A
Posts: 100
Joined: Fri Sep 24, 2021 5:41 am

Re: Electron spin

Postby Eszter Kovacs 1A » Thu Oct 21, 2021 1:45 pm

Yes, according to Hund's rule subshells are filled up by parallel electrons in each orbital before they are paired up.

Jessica Phung 1E
Posts: 56
Joined: Fri Sep 24, 2021 6:25 am

Re: Electron spin

Postby Jessica Phung 1E » Thu Oct 21, 2021 2:09 pm

Yes, this is correct. Just to note, in any case where you see it otherwise, the atom either has excited electrons or the circumstance is nonexistent and thus the answer would be that there are no possible scenarios.

Alex Luong 3H
Posts: 108
Joined: Fri Sep 24, 2021 7:18 am

Re: Electron spin

Postby Alex Luong 3H » Thu Oct 21, 2021 2:11 pm

On that note, does it matter which spin value each electron has? Or does it only matter if they are parallel or paired?

Claire Kim 1F
Posts: 102
Joined: Fri Sep 24, 2021 6:27 am

Re: Electron spin

Postby Claire Kim 1F » Fri Oct 22, 2021 12:23 pm

Gabi_Maldonado_1D wrote:When filling the p,d, and f orbitals with electrons, is it correct to put electrons in each orbital with parallel spins, before pairing the electrons in orbitals and reversing the spin of the second one?



Yes, this is true. This is according to Hund's Rule which states that each orbital needs to have one spin before any of them have a full orbital.

Shreya Thyagarajan Dis1A
Posts: 51
Joined: Fri Sep 24, 2021 5:32 am

Re: Electron spin

Postby Shreya Thyagarajan Dis1A » Fri Oct 22, 2021 4:24 pm

Alex Luong 3I wrote:On that note, does it matter which spin value each electron has? Or does it only matter if they are parallel or paired?

I do believe it matters which spin value the electrons have, because electrons in the same orbital cannot have the same spin.

Jahnavi Srinivas 2H
Posts: 50
Joined: Fri Sep 24, 2021 6:02 am

Re: Electron spin

Postby Jahnavi Srinivas 2H » Fri Oct 22, 2021 5:21 pm

You are correct; Hund's rule states that orbitals must be filled by individual parallel electrons before they are paired with a second electron.


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