Chromium and Copper Electron Configuration Exceptions  [ENDORSED]

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SPandya1F
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Chromium and Copper Electron Configuration Exceptions

Postby SPandya1F » Sun Oct 22, 2017 5:26 pm

Is there an explanation for the chromium and copper electron configuration exception? Do we have to memorize the electron configurations or is there a way to figure it out?

Jessica Schirmer 1J
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Re: Chromium and Copper Electron Configuration Exceptions

Postby Jessica Schirmer 1J » Sun Oct 22, 2017 6:11 pm

The atoms are more stable when the d orbital is either half filled or completely filled versus partially filled, therefore one e- from the 4s orbital is "moved" into the 3d orbital in both cases. I believe the only way to know these exceptions is memorization.

Lorie Seuylemezian-2K
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Re: Chromium and Copper Electron Configuration Exceptions

Postby Lorie Seuylemezian-2K » Mon Oct 23, 2017 11:28 am

Is there a reason for this exception? (the difference in stability)

Chem_Mod
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Re: Chromium and Copper Electron Configuration Exceptions

Postby Chem_Mod » Mon Oct 23, 2017 1:58 pm

This result is from empirical data, there is not a simple explanation for the exception.

Wayland Leung
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Re: Chromium and Copper Electron Configuration Exceptions  [ENDORSED]

Postby Wayland Leung » Mon Oct 23, 2017 2:18 pm

The d-orbitals for Chromium and Copper are only half-filled and fully-filled. Instead of writing Chromium as [Ar]3d^44s^2, you would write the electron configuration as [Ar]3d^54s^1 to fill the d-orbital with five electrons rather than four. The same goes for copper, instead of 9 electrons in the d-orbital and 2 electrons in the s-orbital, you would write it as 10 electrons in the d-orbital and 2 electrons in the s-orbital.

905022356
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Re: Chromium and Copper Electron Configuration Exceptions

Postby 905022356 » Mon Oct 23, 2017 11:04 pm

Cr and Cu are exceptions because they are more 'stable' with a 4s^1 configuration, this makes me wonder, is there any way we can measure or investigate stability experimentally?


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