Short Hand
Moderators: Chem_Mod, Chem_Admin
-
- Posts: 101
- Joined: Sat Aug 17, 2019 12:16 am
Short Hand
Would anyone mind explaining how the short hand for electron configurations works? For example Chromium, Cr: [Ar]3d⁵ 4s¹
How do you choose the element to base the shorthand off of?
How do you choose the element to base the shorthand off of?
Re: Short Hand
You pick the noble gas before the element. Those are the ones on the far right of the periodic table. These are chosen because they have filled electron shells.
-
- Posts: 100
- Joined: Fri Aug 30, 2019 12:16 am
Re: Short Hand
The element in the brackets [ ] is the noble gas from the group before the element you are creating the electron configuration for. This is shorthand because writing this noble gas(far right of periodic table) signifies the electron configuration up to that element. Then, you just have to write out the electron configuration for the most outer shell.
-
- Posts: 102
- Joined: Sat Sep 07, 2019 12:17 am
- Been upvoted: 1 time
Re: Short Hand
So you want to base your shorthand off of the last element in the previous row (the last noble gas before your element). Chromium belongs in period 4 so you'd go to the previous row (period 3) and move to the last element (group 18), which is Argon.
The "s" block consists of groups 1-2, the "p" block of groups 13-18, and the "d" block of groups 3-12, and the "f" block of the inner transition metals. To go from argon to chromium, you have to go through 4s^2 and 3d^4, which is what you'd think to be the configuration of chromium. But chromium actually exists as [Ar] 3d^5 4s^1 because that's just the structure where the repulsion balance and the size of the energy gap between the 3d and 4s orbitals produces the lowest energy for the system (the most energetically stable state).
The "s" block consists of groups 1-2, the "p" block of groups 13-18, and the "d" block of groups 3-12, and the "f" block of the inner transition metals. To go from argon to chromium, you have to go through 4s^2 and 3d^4, which is what you'd think to be the configuration of chromium. But chromium actually exists as [Ar] 3d^5 4s^1 because that's just the structure where the repulsion balance and the size of the energy gap between the 3d and 4s orbitals produces the lowest energy for the system (the most energetically stable state).
-
- Posts: 50
- Joined: Mon Jun 17, 2019 7:22 am
Re: Short Hand
ONce you get the base configuration, usually you don't want to have the long electron configuration, so we use the elements in the far-right column of the periodic table (starting with Helium and ending with Radon) for short-hand. Basically once you have the electron configuration, in the event that there are twelve electrons in an atom, you'll take the noble gas that has a electron number lower than that, in this case, Neon [Ne] which has ten electrons and subtract it from the initial number leaving you with five. So instead of your electron configuration being 1s^2 2s^2 2p^6 3s^2 3p^3, your electron configuration is [Ne]3s^2 3p^3. Hope this helps
-
- Posts: 101
- Joined: Sat Jul 20, 2019 12:15 am
Re: Short Hand
You put the last noble gas configuration in brackets and then continue using spdf normally after that.
-
- Posts: 102
- Joined: Sat Aug 17, 2019 12:18 am
-
- Posts: 114
- Joined: Fri Aug 30, 2019 12:17 am
Re: Short Hand
Refer to the previous noble gas and put the name of that in brackets and then continue to write the configuration. Basically we just act as if the noble gas in the brackets acts as the configuration for the noble gas, so we would continue writing configuration as if we wrote the configuration up till that noble gas.
-
- Posts: 97
- Joined: Thu Jul 25, 2019 12:17 am
Re: Short Hand
Because the noble gases have their outer shell completely full, they are used in shorthand electron configurations. The noble gas of the period above that of the electron in focus is written in brackets, and then the valence electrons are written in after the brackets. This makes electron configurations easy to read and understand.
Re: Short Hand
since the configurations continue to get longer and longer, you can start the longer configurations with an abbreviation of the noble gas that comes before it. The noble gases are the column all the way to the right and they have full outer shells, which makes it possible for us to use them when doing the shorthand configurations.
-
- Posts: 51
- Joined: Wed Sep 18, 2019 12:19 am
-
- Posts: 113
- Joined: Sat Jul 20, 2019 12:15 am
Re: Short Hand
To write in short hand, find the specific element that you will use. Let’s use S for this example. Find the preceding noble gas first, which is in group 18 in the preceding period. In S’s case, it is Ne. You would write Ne in brackets first at the beginning of the configuration then finish it off normally with the spdf notation. So, for S, the noble gas configuration or short hand would be the following: [Ne]3s^2 3p^4.
Return to “Electron Configurations for Multi-Electron Atoms”
Who is online
Users browsing this forum: No registered users and 16 guests