Electron Configuration for Copper

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Drew Wood-Palmer 1B
Posts: 2
Joined: Fri Sep 25, 2015 3:00 am

Electron Configuration for Copper

Postby Drew Wood-Palmer 1B » Tue Oct 13, 2015 10:36 pm

How is the electron configuration of Cu+ 3d^10, when no element on the periodic table has that configuration?

Laila Sathe 1D
Posts: 27
Joined: Fri Sep 25, 2015 3:00 am

Re: Electron Configuration for Copper

Postby Laila Sathe 1D » Wed Oct 14, 2015 10:28 am

It's because copper is one of the exceptions to regular orbital filling rules: copper's electrons completely fill the 3d orbital and leave the 4s orbital with only one electron. Because the 4s orbital is a lower energy orbital than the 3d orbitals, the valence electron that is lost when Cu ionizes to Cu+ comes from the 4s orbital.

Cu:[Ar]3d104s1
Cu+:[Ar]3d10

Jessica Manzano 1B
Posts: 23
Joined: Fri Sep 25, 2015 3:00 am

Re: Electron Configuration for Copper

Postby Jessica Manzano 1B » Wed Oct 14, 2015 10:30 am

The ground state electron configuration of Cu is [Ar] 3d10 4s1. Although 4s is filled before 3d, 3d becomes lower in energy than 4s once it is filled with electrons, which is why 4s1 is listed after 3d10. One may expect the electron configuration of Cu to be [Ar] 3d9 4s2, but this is not true because electron configurations are most stable when they have the lowest energy possible. To give the electron configuration of Cu the lowest energy possible, one electron from the 4s subshell enters the 3d subshell. Half full and full d subshells have lower energy due to lesser electron repulsion, so in moving the one electron from 4s to 3d to create a full 3d10 subshell, Cu becomes more stable. This leaves the one electron in 4s1 as the outermost and highest energy valence electron in Cu. Because of the shielding effect of the core electrons in Cu, this outermost valence electron is the easiest to remove to create the cation Cu+.


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