m(subscript L)

Moderators: Chem_Mod, Chem_Admin

Ellen Tsai 3D
Posts: 55
Joined: Fri Sep 24, 2021 5:55 am

m(subscript L)

Postby Ellen Tsai 3D » Thu Oct 21, 2021 5:31 pm

I'm just a little confused at how one can tell what m(l) is. Like I understand that if you're given 4p2 n = 4, l = 1 and m(l) can be anything from -1, 0 , 1 but how do you know exactly. Thank you!

Anna Hilger 3H
Posts: 98
Joined: Fri Sep 24, 2021 7:09 am
Been upvoted: 1 time

Re: m(subscript L)

Postby Anna Hilger 3H » Thu Oct 21, 2021 5:42 pm

Hi,

It depends on the number of valence electrons. For example, 4p^2, there are 2 valence electrons. So, the first electron goes into either -1 or +1 and then the second goes into 0. I don't know if this makes sense, but it is how I understand it.

Hope this helps :)

Ellen Tsai 3D
Posts: 55
Joined: Fri Sep 24, 2021 5:55 am

Re: m(subscript L)

Postby Ellen Tsai 3D » Thu Oct 21, 2021 5:52 pm

Anna Hilger 2G wrote:Hi,

It depends on the number of valence electrons. For example, 4p^2, there are 2 valence electrons. So, the first electron goes into either -1 or +1 and then the second goes into 0. I don't know if this makes sense, but it is how I understand it.

Hope this helps :)


wait so how do uk whether it goes into -1 or +1 first...

bree_wray_14a
Posts: 50
Joined: Fri Sep 24, 2021 6:33 am

Re: m(subscript L)

Postby bree_wray_14a » Thu Oct 21, 2021 8:56 pm

For the s orbital, the maximum amount of orbitals is 1. For the p orbital, the max orbital number is 3. for d orbital it is 5. and for f orbital it is 7. each ml value begins with zero and move outward in both directions from there.

I hope that makes sense!!!

Anna Hilger 3H
Posts: 98
Joined: Fri Sep 24, 2021 7:09 am
Been upvoted: 1 time

Re: m(subscript L)

Postby Anna Hilger 3H » Fri Oct 22, 2021 7:51 pm

Ellen Tsai 3D wrote:
Anna Hilger 2G wrote:Hi,

It depends on the number of valence electrons. For example, 4p^2, there are 2 valence electrons. So, the first electron goes into either -1 or +1 and then the second goes into 0. I don't know if this makes sense, but it is how I understand it.

Hope this helps :)


wait so how do uk whether it goes into -1 or +1 first...



I don't know. My TA said either it would be in -1 or +1, so I guess you need complicated math to find out.

Sanjana Sivakumar 2E
Posts: 125
Joined: Fri Sep 24, 2021 7:30 am
Been upvoted: 2 times

Re: m(subscript L)

Postby Sanjana Sivakumar 2E » Fri Oct 22, 2021 9:26 pm

Ellen Tsai 3D wrote:
Anna Hilger 2G wrote:Hi,

It depends on the number of valence electrons. For example, 4p^2, there are 2 valence electrons. So, the first electron goes into either -1 or +1 and then the second goes into 0. I don't know if this makes sense, but it is how I understand it.

Hope this helps :)


wait so how do uk whether it goes into -1 or +1 first...



Hello!

From what I understand, the ml represents the orientation of the orbital. And since orientation is in 3D, it's non-directional. I can turn the sphere any way and relabel the axises, but the sphere itself won't change. So, I think it wouldn't matter which goes first. And I think that's as much as we need to know. I'm not sure if I'm explaining this right, but this is what I think it is.

Hope this helps!

Kathryn Heinemeier 3H
Posts: 104
Joined: Fri Sep 24, 2021 5:09 am

Re: m(subscript L)

Postby Kathryn Heinemeier 3H » Sat Oct 23, 2021 12:02 am

it depends on what orbital it is because a s orbital will be 0 while a p orbital will be -1,0,1

Jane Wang 1E
Posts: 115
Joined: Fri Sep 24, 2021 6:36 am

Re: m(subscript L)

Postby Jane Wang 1E » Sat Oct 23, 2021 12:21 am

Hi! Basically m(l) is the magnetic quantum number, and it represents the orbital, for example, in p subshell, it has Px, Py and Pz three orbitals. Plus, the value of m(l) are from -l to +l, including 0.

Hope this helps!

Mona Reddy Kurra 1J
Posts: 100
Joined: Fri Sep 24, 2021 5:16 am
Been upvoted: 1 time

Re: m(subscript L)

Postby Mona Reddy Kurra 1J » Sat Oct 23, 2021 1:05 pm

Hi! Similar to what the previous posts said, refers to the specific orbital's orientation. My TA said that because of this, the values are arbitrarily assigned. Although you can determine what the possible values of are based on the subshell information, Hund's rule, and the number of electrons that the atom has, the actual assignment of the value to each electron doesn't really matter since the orientation is based on our own perspective of the 3D space. I hope that helps!

Elsie_Lin_2K
Posts: 103
Joined: Fri Sep 24, 2021 5:08 am

Re: m(subscript L)

Postby Elsie_Lin_2K » Sat Oct 23, 2021 1:45 pm

m(l) represents the orientation of the orbitals so in order to determine the value of m(l) you would have to look at the orbital by looking at the value of l. You can calculate the values of m(l) using l, l-1,...-l. The different orbitals have a maximum number of orientations. For example, there are 3 in the p orbital and 5 in the d orbital.

Isabelle Kim 3E
Posts: 131
Joined: Fri Sep 24, 2021 6:17 am
Been upvoted: 1 time

Re: m(subscript L)

Postby Isabelle Kim 3E » Sat Oct 23, 2021 1:54 pm

Kind of to reiterate what everybody else has been saying, you've got the right idea for sure but to further clarify - this quantum # (ml) describes the possible coordination of the electrons of a particular atom
So using the l value, we may approximate the possible electron configurations within that given l value, which is providing us the shape of orbital (s, p, d, f).

Niyati 1F
Posts: 90
Joined: Fri Sep 24, 2021 7:04 am

Re: m(subscript L)

Postby Niyati 1F » Sun Oct 24, 2021 12:35 pm

The ml value is based on the l value. It will range from -l to +l. So the s subshell has a ml value of 0, the p can range from -1, 0, 1, the d could be -2, -1, 0, 1, 2, etc.


Return to “Electron Configurations for Multi-Electron Atoms”

Who is online

Users browsing this forum: No registered users and 4 guests