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Its important to remember that there are two exceptions in the first row of the d block. Cr or Chromium's configuration is [Ar]3d^5 4s^1 and the other exception is Cu or copper which has the configuration [Ar]3d^10 4s^1. I believe one of the TA's mentioned that there are more exceptions further down the periodic table but to just focus on the 1st row of the d block.
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