Partial Bond

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WYacob_2C
Posts: 102
Joined: Sat Jul 20, 2019 12:16 am

Partial Bond

Postby WYacob_2C » Fri Oct 25, 2019 11:13 pm

Can someone further explain the idea of having a "partial bond" character? It was discussed in lecture when we were going over the nitrate ion.

jisulee1C
Posts: 149
Joined: Thu Jul 25, 2019 12:17 am

Re: Partial Bond

Postby jisulee1C » Sat Oct 26, 2019 11:46 am

Partial bonds are when the structure can resonate or flip between two or more conformations. The nitrate ion has partial bonds because the double bonded oxygen can be at multiple locations (3 positions) therefore the actual structure would be a blend between the 3 structures.

AnnikaMittelhauser4E
Posts: 50
Joined: Fri Aug 30, 2019 12:18 am

Re: Partial Bond

Postby AnnikaMittelhauser4E » Sat Oct 26, 2019 11:53 am

To add on, partial bonds have bond lengths that are also a blend b/w the two structures. So, since the nitrate bonds can be thought of as a blend between double and single bonds, the length is between that of a double (shorter) and single bond (longer) involving nitrogen and oxygen in a non-resonance molecule. In the case of nitrate, the actual bond length is closer to a single bond I believe because in the possible Lewis structures, there are two single bonds and one double.


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