Identifying a hydroxyl group from the molecular formula

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Shelby Y 1K
Posts: 48
Joined: Fri Sep 27, 2024 7:26 am

Identifying a hydroxyl group from the molecular formula

Postby Shelby Y 1K » Sat Nov 30, 2024 6:56 pm

Hi! How do we identify whether there's a hydroxyl group just from the molecular formula? For example, CH2 = CHCHO doesn't have a hydroxyl group, though the H and O are written next to each other in this specific example. Do we just have to use trial-and-error/formal charge, or is there another parameter that we go by? I've also been told that we should, for the most part, assume that there isn't a hydroxyl group.

Kenah Angeles 2C
Posts: 46
Joined: Fri Sep 27, 2024 8:55 am

Re: Identifying a hydroxyl group from the molecular formula

Postby Kenah Angeles 2C » Sat Nov 30, 2024 8:47 pm

Hi! Correct me if I'm wrong but to identify a hydroxyl group (-OH) from a molecular formula, consider the bonding structure implied by the formula and the typical valencies of atoms (C = 4, O = 2, H = 1). In CH₂=CHCHO, the oxygen is part of an aldehyde group (-CHO), not a hydroxyl. Structural clues and chemical logic, rather than just the sequence of atoms, guide the identification.

I'm a little confused with this as well so let me know if it may be different than what I said!


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