(SO3)2- Lewis Structure Formal Charge

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Edgar Khachatryan 3G
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(SO3)2- Lewis Structure Formal Charge

Postby Edgar Khachatryan 3G » Sun Oct 30, 2016 11:10 pm

Hi.

The Lewis Structure for sulfite has 3 resonance structures in which the Sulfur has a formal charge of 0 and two of the oxygens have a formal charge of -1.

Why couldn't there be a 3 double bonds instead? Wouldn't this contribute to Sulfur having a formal charge of -2 and the oxygens having a formal charge of 0?

What makes the former preferable over the latter?

Thank you!

Chem_Mod
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Re: (SO3)2- Lewis Structure Formal Charge

Postby Chem_Mod » Mon Oct 31, 2016 11:34 am

It is best to minimize formal charges on the central atom. Remember it is supposed to be an atom of low electronegativity (low ionization energy). Thus, a formal charge of -2 on a central sulfur atom is unfavorable.


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