Exceptions to octet rule

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Nancy Hu - 4E
Posts: 30
Joined: Fri Sep 28, 2018 12:28 am

Exceptions to octet rule

Postby Nancy Hu - 4E » Sat Oct 27, 2018 9:19 am

Can someone help explain why H, He, Li, and Be are exceptions to the octet rule?

Sofia Ban
Posts: 80
Joined: Fri Sep 28, 2018 12:25 am

Re: Exceptions to octet rule

Postby Sofia Ban » Sat Oct 27, 2018 10:17 am

H and He are exceptions to the Octet Rule because for them, a full shell contains only 2 electrons (1s shell). Li and Be are metals, so they're likely to lose electrons, therefore becoming cations (Li+, Be2+). When this happens, they revert to the "noble gas" configuration of He, which is 2 electrons. So for these four elements, a full shell consists of 2 electrons, not eight.

In addition, the H-atom doesn't need to fill its valence shell when forming ionic bonds. In an HF molecule, the H-atom is the cation, meaning it gave up its single valence electron to bond with the F-atom. The H-atom doesn't have a full valence shell, but rather has no valence shell to fill while the F-atom gains an electron to fill its valence shell.


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