bond lengths

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connie 2C
Posts: 106
Joined: Thu Jul 11, 2019 12:17 am

bond lengths

Postby connie 2C » Wed Oct 23, 2019 8:57 pm

professor lavelle said something about how double bond lengths are 1.2 A and how single bond lengths are 1.4 A. how come the bond lengths were 1.24 A for the example from today's lecture?

Anika Chakrabarti 1A
Posts: 102
Joined: Sat Aug 24, 2019 12:17 am

Re: bond lengths

Postby Anika Chakrabarti 1A » Wed Oct 23, 2019 9:06 pm

I think this happens because the double bond can occur at three different locations (remember the three different structure diagrams for NO3 that he showed in class), so this bond length of 1.24 A is kind of like an average or combination of the different structures.

Ying Yan 1F
Posts: 101
Joined: Fri Aug 02, 2019 12:16 am

Re: bond lengths

Postby Ying Yan 1F » Thu Oct 24, 2019 1:26 pm

The bond length was 1.24 Angstrom because that molecules was exhibits resonance. The 1.24 Angstrom means that the bonds in the NO3 molecule are hybrid between a double bond and a single bond. Hope that helps!

romina_4C
Posts: 100
Joined: Thu Jul 11, 2019 12:17 am

Re: bond lengths

Postby romina_4C » Thu Oct 24, 2019 1:50 pm

Adding on to the other answers, the molecule has resonance, and the more resonance structures a molecule has, the more stable it is.

McKenna_4A
Posts: 115
Joined: Sat Aug 24, 2019 12:18 am

Re: bond lengths

Postby McKenna_4A » Thu Oct 24, 2019 3:21 pm

Also remember that this bond isn't actually "rotating" around the atom. Lots of chem textbooks make it out to be like this. Just remember that the bond lengths will be an average.


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