bond length
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bond length
are we supposed to know how to calculate bond length?
if so what equation or how do we do that?
thank you
if so what equation or how do we do that?
thank you
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Re: bond length
I don't believe so! I think we just need to know the lengths of bonds relative to others, so a double bond is shorter than a single bond, a triple bond is shorter than a double bond, etc.
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Re: bond length
Agree with what is said above^. Maybe sometimes in resonance structures we will be asked to find the actual bond length when there are say two double bonds and one single bond that can be in any place of the three bonds, in that case we just find the average of all the bond lengths. I'm not sure why it would simply be the average but even if not it would be some value close to the average.
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Re: bond length
so how are we able to see which bonds are longer or smaller? like in Q11 of the sapling week 5 and 6 HW?
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Re: bond length
Like most people have said, i don't think we necessarily have to know how to calculate the bond length, but we should know which bonds are longer and which bonds are shorter; so for example double bonds are shorter than single bonds, but triple bonds are shorter than double bonds, single bonds are always the longest. Hope this helped :)
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Re: bond length
No, we are not. If we need to know bond lengths for to answer a question, we should be given them.
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Re: bond length
I think the bond lengths would be given if we needed to calculate, but like what other people have been saying, to calculate the resonance structure bonds you just need to calculate the average of all the bonds (triple, double, single). The more single bonds, the longer the resonance bonds would be, and the more triple or double bonds, the shorter.
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Re: bond length
No, bond lengths will be given in problems if we need the exact length. You should still know the relationship between bond length and strength with single, double, and triple bonds though.
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Re: bond length
We don't need to know how to calculate them but we do need to know which bond lengths are stronger and shorter compared to which bond lengths are longer and weaker.
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Re: bond length
We do not need to know how to calculate for bond lengths. In lectures, Dr. Lavelle told us that the values given to us were ones that he looked up, meaning that we wouldn't be expected to find them ourselves. All you need to know is that the bonds from longest to shortest are single, double, triple and how the length compares to the strength of the bond.
Re: bond length
We dont need to specific bond lengths but we should know that in resonance hybrid structures all bond lengths are equal(average of the different lengths) and the higher the electron density of the bond, the shorter the bond length
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Re: bond length
Yeah, I don't think we need to know the exact bond length because Professor Lavelle said in his lectures that the examples of bond length are from research and that we don't need to memorize them. Also, we just need to know the general trends of bond length through atomic radius trend and other concepts.
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Re: bond length
We don't need to know the exact numbers for bond length but know that single bonds are the longest, then double bonds, then triple bonds are the shortest. The length tells us the strength; the longer the bond, the weaker it is.
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Re: bond length
From everything I have seen so far, the bond length is usually given. I think it would be more beneficial to know what factors contribute to bond length. For example, size of an atom may increase the bond length. Also know that the greater the bond length, the weaker the bond will be.
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Re: bond length
I do not believe that we are expected to calculate bond length. BUT, it is important to know trends for bond length. Know that bond length is inversely proportional to bond strength. Also make sure to remember that the larger an atom is, the larger the bond length will be.
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Re: bond length
The bond length will most likely be given in the problem. We could use the bond length to determine which lewis structure best fits the molecule or to determine how tightly held the shared electrons are between atoms.
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Re: bond length
I believe we don't need to solve for the exact bond length, but it is possible to estimate what the bond length will be without having to solve for it based on information given. If a molecule has 4 bonds and three are single bonds, then the bond length will be closer to the value given for the expected bond length for single bonds and it will be within the range given for the expected single bond length to the expected double bond length.
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Re: bond length
Hi, I don't think we need to calculate the actual bond length. As long as you know some characters like the longer length the weaker strength, you should be fine.
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Re: bond length
Tiffanny_Carranza_2D wrote:are we supposed to know how to calculate bond length?
if so what equation or how do we do that?
thank you
Hi Tiffany!
In this class, we do not need to calculate the actual bond length, as it is usually given, both the theoretical and the experimentally observed one. However, we will be asked on the average bond length of the molecule, and when that happens, you use the theoretical bond length that is given to you. For example, if they said that C-O is 164 pm and C=O is 143 pm (these are random numbers, not official ones), and you were told to calculate the average bond length, then you would add up the total bond length and divide it by the number of bonds. If you had 1 double bond and 2 single bonds, then you would write (2(164)+1(143)/3 because you have two single bonds and 1 double bond, making a total of three bonds. Go ahead and solve it.
If you got 157pm, then you are correct!
I know you may not have needed the example, but I really hope that clarifies with what we need to do in the class.
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Re: bond length
No, I don't think we're expected to calculate bond length as of right now, just know certain trends and ideas like triple bonds are the shortest while single bonds are the longest, and the bigger atoms have longer bond lengths when bonded with another, etc.
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Re: bond length
I don't think we need to calculate the exact bond lengths, but you should know the difference between the general bond lengths. Which ones are stronger and shorter vs. weaker and longer in regards to the single, double, and triple bonds.
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Re: bond length
As others have mentioned, the bond length should be given to solve such. It's more important to know lengths in regards to the number of bonds, e.g Single bonds > Double bonds > Triple bonds.
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Re: bond length
nope but we do need to know the length of the bonds in regards to the number of bonds
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Re: bond length
I do not think that we need to know how to calculate bond length necessarily. However, we should definitely be able to differentiate bond length based on the number of bonds. The higher the bond order (single bond, double bond, triple bond), the shorter the bond length.
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Re: bond length
I’m pretty sure we’re not gonna need to know how to solve for/calculate the bond length for the upcoming midterm!
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Re: bond length
We just need to be able to compare them, no exact numbers. Just know that double bonds are stronger than single bonds, and that larger molecules have weaker bonds.
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Re: bond length
We don't need to know the exact numbers but we do need to know how to compare them in terms of strength and length.
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Re: bond length
we won't need to know anything exact, but know that the order from longest to shortest goes single>double>triple
Re: bond length
no- all bond lengths in specific numbers should be given to us. If we ever have to figure out a bond length, just use a general periodic trend to make an estimate.
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Re: bond length
No! You just need to know the concepts. For example, multiple bonds have a shorter bond length. Weaker bonds are longer. Lone pairs on neighboring atoms also repel each other, which then in turn weakens the bond.
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Re: bond length
Here's hoping that all we need to know are the basic concepts behind bond length, which I'm pretty sure is the case.
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