Bond Lengths
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Bond Lengths
For resonance structures, is it favored to stack up on bonds or have as many single bonds as you can?
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Re: Bond Lengths
Hi! It really depends on the molecule that is in question. The main point of resonance is finding a way to minimize formal charges, so for some molecules this might mean removing bonds and adding in lone pairs, but for others this might entail removing lone pairs and adding in bonds. Because of this, there really is no set rule for whether single or multiple bonds is better, you have to take in by a case-by-case approach.
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Re: Bond Lengths
It depends on the situation and what elements are in the molecule. The amount of bonds vs lone pairs will affect the formal change of each element so that will be what you need to look at in each scenario.
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Re: Bond Lengths
The amount of single/double/triple bonds is less important than the formal charges on each atom. The goal is to get the formal charges as close to zero as possible and have any negative formal charge on the most electronegative element. Because each bond subtracts 1 from the number of valence electrons to contribute to the formal charge, the number of bonds can be adjusted accordingly, depending on the molecule, to obtain the most ideal formal charges for the most stable structure.
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Re: Bond Lengths
You will need to take into account the atoms in the molecule for the bonds in a molecule. For halogens, they prefer having a single bond, as they have 7 valence electrons and a single bond is the most stable for a halogen (with a formal charge of zero!). For group 6 elements (like oxygen), they prefer a double bond, as they have 6 valence electrons and a double bond with two lone pairs achieves a formal charge of zero. Valence electrons are often indicators of the number of bonds needed.
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Re: Bond Lengths
it really depends on the molecules, the best strategy i'd offer you is to check the formal charges
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Re: Bond Lengths
The formal charge is more important than the specific bonds between atoms when it comes to resonance structures. The structure with the least number of atoms with formal charges will be the favored structure.
Re: Bond Lengths
It would depend on the specific molecule that you are looking at, and its formal charges.
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Re: Bond Lengths
In regards to resonance structures, it's not necessarily the amount of bonds that's important, but rather the formal charge. It is ideal for the formal charges to be as close to zero as possible, and the bonds can affect that, but it honestly depends on the molecule.
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Re: Bond Lengths
Hello,
It really depends not eh molecule you have. You can start of with single bonds if it works but then you really ant to look t the formal charges. The formal charges will dictate if you need single, double, or even triple bonds in that place.
Hope this helps.
It really depends not eh molecule you have. You can start of with single bonds if it works but then you really ant to look t the formal charges. The formal charges will dictate if you need single, double, or even triple bonds in that place.
Hope this helps.
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Re: Bond Lengths
For this situation, it is dependent on the formal charges of the molecule and the goal such as trying to find a plausible resonance structure or reduce the number of charges as close to 0 as possible!
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Re: Bond Lengths
It depends on the formal charges. If formal charges are closer to 0 with more single bonds, then yes. If not, then no.
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Re: Bond Lengths
there isn't a set rule on what type of bonds you should use. rather try focusing more on formal charge and getting all the atoms to have a formal charge of 0
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Re: Bond Lengths
hi, it does not depend on the type of bond to determine the most stable structure. It depends on the formal charges of the atoms, which should normally be close to zero.
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Re: Bond Lengths
Hi, the formal charge of the molecule is most important rather than the bond type as that varies from molecule to molecule. So it is best to keep in mind the amount of bonds and the lone pairs as those effect formal charge.
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Re: Bond Lengths
Resonance structures have bond lengths that are determined by formal charge of each element involved in the structure
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Re: Bond Lengths
Stacking bonds depends on the molecule itself and the formal charge for each atom (with the point of minimizing formal charge as much as possible).
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Re: Bond Lengths
Stacking bonds really depends on the molecule and the most stable resonance structure in question. Sometimes, stacking bonds (ie. double or triple) results in a more neutral formal charge that balances itself out thus resulting in a more balanced structure or molecules while other times a single bond is more pertinent for this purpose.
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Re: Bond Lengths
Hi,
It depends on the molecules and their formal charges. Also, the formal charges of the atoms/molecules must be close to zero.
It depends on the molecules and their formal charges. Also, the formal charges of the atoms/molecules must be close to zero.
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Re: Bond Lengths
Hi,
It will depend on the formal charges of the molecules since the charge of each molecule will determine the use of the bond.
It will depend on the formal charges of the molecules since the charge of each molecule will determine the use of the bond.
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Re: Bond Lengths
When dealing with resonance structures, you would like each atom to have 0 or nearest to 0 formal charge. So having the least amount of single bonds does not matter, unless the atoms in the molecule have 0 or nearest to 0 formal charge (like CH4 that has only single bonds and 0 formal charge all around). But with a molecule like SO4, the best resonance structure is one that has two double bonds and two single bonds because the formal charges become 0 and -1 and its atoms. Which is more reasonable than only having single bonds on this molecule, making -1 FC on H and +2 FC on S.
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Re: Bond Lengths
I don't think it is favored to stack bonds or have single bonds. I believe that the arrangement that is favored is just the one that has a formal charge closest to 0.
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Re: Bond Lengths
It depends on how many electrons you have to create bonds with. If you can't make the atoms that need an octet have an octet with single bonds, you will have to start making double or triple bonds.
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Re: Bond Lengths
It mostly depends on the molecule in question and trying to make the formal charge closest to zero because it all varies
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Re: Bond Lengths
It depends on the formals charges, and least amount of charge is preferred because it will be the most stable.
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Re: Bond Lengths
It depends on which arrangement of the structure will give you the most ideal formal charge, or in other words the arrangement that is closest to 0.
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Re: Bond Lengths
In order to figure out whether or not to create single, double, or triple bonds, it's important to look at the formal charges and resonant structures. The resonant structure with the least amount of charge will be the most probable structure, thus leading to a structure that has a certain amount of single, double, and triple bonds.
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Re: Bond Lengths
You should assign different types of bonds (single, double, triple) in order to minimize the formal charge on atoms. And for bond length, from longest to shortest, it's single, double, then triple
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Re: Bond Lengths
It would depend on the formal charge of the molecule. You want to have a formal charge equal to 0 or as close as possible to 0.
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Re: Bond Lengths
This can only be determined by calculating the formal charge. You would have to see which way would be the one that's closest to a formal charge of 0, and you would go for that one.
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