Cation polarizing power

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Arya_Naeim_1H
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Cation polarizing power

Postby Arya_Naeim_1H » Thu Dec 07, 2023 11:43 am

I was looking at a UA worksheet that said that Mg2+ has a higher polarizing power than Li+. I know that more highly charged cations have a higher polarizing power but Li+ is one row above Mg2+ so I would assume Li+ is smaller. Can someone explain which one has the higher polarizing power and why?

Maille Flynn 3H
Posts: 91
Joined: Fri Sep 29, 2023 11:02 am

Re: Cation polarizing power

Postby Maille Flynn 3H » Thu Dec 07, 2023 12:25 pm

Even though Li is smaller than Mg, Mg2+ is actually slightly smaller than Li+. There is a table in the textbook in 1F.3 of ionic radii, and Li+ is bigger than Mg2+. So because of that, Mg2+ will have the higher polarizing power.


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