3.85 part b

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Jade Corpus-Sapida 1G
Posts: 35
Joined: Fri Apr 06, 2018 11:02 am

3.85 part b

Postby Jade Corpus-Sapida 1G » Tue May 22, 2018 9:11 pm

In this problem it asks to arrange the following molecules/ions in order of decreasing lengths: SO2, SO3, and SO32-. The answer is SO32- > SO2 ~SO3. I understand why SO32- has the longest length, however I don't understand why the other two would have equal/same lengths? If this were to be on a test how would we know that they were equal?

Jade Corpus-Sapida 1G
Posts: 35
Joined: Fri Apr 06, 2018 11:02 am

Re: 3.85 part b

Postby Jade Corpus-Sapida 1G » Tue May 22, 2018 9:12 pm

or would this just be known by looking up these values in the back of the book/online? or can it be calculated?

Emma Leshan 1B
Posts: 30
Joined: Fri Apr 06, 2018 11:03 am

Re: 3.85 part b

Postby Emma Leshan 1B » Sun May 27, 2018 10:11 am

Both Lewis structures have one double bonded O and the other(s) are single bonded. Because of resonance, the double bonds are shared throughout the molecule. This makes the bond lengths approximately equal in the molecules even though technically SO2 should be a little shorter due to the double bond being shared at 2 bonds instead of 3.

ErinKim1I
Posts: 31
Joined: Fri Apr 06, 2018 11:03 am

Re: 3.85 part b

Postby ErinKim1I » Sun May 27, 2018 12:25 pm

When there is resonance, electrons are delocalized and so the bond length distribution is somewhere between the single and double bond in the structure.


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