Vaporization

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KiaraTenorio_14B
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Joined: Fri Sep 24, 2021 5:38 am

Vaporization

Postby KiaraTenorio_14B » Sun Dec 05, 2021 11:18 pm

To determine which elements have the have the highest enthalpy energy for vaporization does this depend on the bond strength and the bond type?

AnoushkaBhat2J
Posts: 105
Joined: Fri Sep 24, 2021 6:23 am

Re: Vaporization

Postby AnoushkaBhat2J » Sun Dec 05, 2021 11:22 pm

KiaraTenorio_14A wrote:To determine which elements have the have the highest enthalpy energy for vaporization does this depend on the bond strength and the bond type?



I think this refers to the intermolecular forces (LDF, H-bonding, dipole-dipole, etc), since highest enthalpy energy for vaporization is taking about the energy required to make 1g of liquid compound into a gas (so you would need to break the IMFs between the liquid molecules).

chemoyku dis 1B
Posts: 80
Joined: Fri Sep 24, 2021 6:55 am

Re: Vaporization

Postby chemoyku dis 1B » Sun Dec 05, 2021 11:23 pm

Hi!

When we are looking at enthalpy of vapourisation, we are looking at its interaction with neighbouring atoms. This is where the intermolecular forces come in.

Rather than bond strength/length, we look at the intermolecular forces that exist between the molecules. For example water has hydrogen bonding with other water molecules and therefore its enthalpy of vapourisation is high.

I hope this helped.

305805394
Posts: 56
Joined: Fri Sep 24, 2021 6:41 am

Re: Vaporization

Postby 305805394 » Sun Dec 05, 2021 11:30 pm

Hi,

as a substance is being vaporized, its intermolecular distance is enlarged. Therefore, the molecule with the highest enthalpy of vaporization would exists the highest intermolecular forces.

Therefore, you should find the molecule with the strongest intermolecular forces(based on what we've learned now, it's probably the hydrogen bond I guess).

Hope this could address your concerns.

Furkan Acar 3C
Posts: 114
Joined: Fri Sep 24, 2021 6:47 am

Re: Vaporization

Postby Furkan Acar 3C » Sun Dec 05, 2021 11:32 pm

It depends on the intermolecular forces if I remember correctly. Don’t really know too much to comment further about it.

Brooklyn Burgess 3L
Posts: 111
Joined: Fri Sep 24, 2021 5:42 am

Re: Vaporization

Postby Brooklyn Burgess 3L » Mon Dec 06, 2021 12:44 am

High vaporization (as well as a high boiling point) have hydrogen bonding.

Nicola Higgins 14B
Posts: 103
Joined: Fri Sep 24, 2021 5:41 am

Re: Vaporization

Postby Nicola Higgins 14B » Mon Dec 06, 2021 9:11 am

I know that a high enthalpy energy means a high boiling point, so we consider intermolecular forces when determining enthalpy values.

cnyland
Posts: 99
Joined: Fri Sep 24, 2021 7:08 am

Re: Vaporization

Postby cnyland » Mon Dec 06, 2021 11:38 am

This would have to do with whichever has the higher intermolecular forces.


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