(Polar molecules, Non-polar molecules, etc.)
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If I understand what you are asking correctly, You look at the number of bonding regions (bonds and lone pairs) that a central atom in a molecule has. For Example, CH4 has 4 bonding regions, and will thus be sp3 hybridization. Hope this helped!
In fact, the number of regions of electron density (number of lone pairs (count two as a pair) and bonds (single, double, triple all count as one)) will always be able to tell the hybridization configuration.
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