Bond Angle of Sulfite Ion

(Polar molecules, Non-polar molecules, etc.)

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Esther Ahn 4I
Posts: 30
Joined: Fri Sep 28, 2018 12:29 am

Bond Angle of Sulfite Ion

Postby Esther Ahn 4I » Thu Nov 15, 2018 11:44 pm

In lecture Dr. Lavelle mentioned that although sulfite has 4 electron pairs arranged tetrahedrally the O-S-O bond angles are 106 degrees and not the expected 109.5 degrees. Can someone please explain why?

Jack Mitchell 3J
Posts: 24
Joined: Fri Sep 28, 2018 12:24 am

Re: Bond Angle of Sulfite Ion

Postby Jack Mitchell 3J » Thu Nov 15, 2018 11:47 pm

When there is a lone pair of electrons, they have a greater repulsion against the two atoms, so the two Oxygen atoms will be closer together because the lone pair is pushing them closer.

Kailey Nichols 4B
Posts: 30
Joined: Fri Sep 28, 2018 12:28 am

Re: Bond Angle of Sulfite Ion

Postby Kailey Nichols 4B » Fri Nov 16, 2018 12:03 am

Similar to how the lone pair of electrons in water cause the bond angle between the H atoms to be less than 109.5 degrees, the lone pair of electrons causes the O-S-O angles to also be less than 109.5 degrees (since lone pair-bonding repulsion is stronger than bonding-bonding repulsion and thus the lone pair of electrons in SO32- pushes the O atoms closer)
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