Sigma/Pi bonds

(Polar molecules, Non-polar molecules, etc.)

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chris_tsai_4H
Posts: 52
Joined: Fri Sep 28, 2018 12:26 am

Sigma/Pi bonds

Postby chris_tsai_4H » Sun Nov 18, 2018 8:49 pm

How do you determine the difference between sigma and pi bonds?

Alexandra Ortega 4D
Posts: 31
Joined: Wed Oct 03, 2018 12:17 am

Re: Sigma/Pi bonds

Postby Alexandra Ortega 4D » Sun Nov 18, 2018 8:55 pm

Sigma bonds usually interact end to end and allow rotation of bonded atoms, while pi bonds overlap side by side and do not allow rotation of bound atoms. Single bonds consist of only one sigma bonds and double bonds consist of one sigma and one pi bond. So, the first bond between to atoms must be a sigma bond and the rest are pi bonds.

amogha_koka3I
Posts: 62
Joined: Fri Sep 28, 2018 12:24 am

Re: Sigma/Pi bonds

Postby amogha_koka3I » Sun Nov 18, 2018 9:03 pm

So just to confirm there is no more than one sigma bond in any bond/atom interaction?

104904344
Posts: 27
Joined: Fri Sep 28, 2018 12:27 am

Re: Sigma/Pi bonds

Postby 104904344 » Sun Nov 18, 2018 10:44 pm

I believe there can be more than one sigma bond in a molecule, but not between two atoms.

404536963
Posts: 29
Joined: Fri Feb 02, 2018 3:02 am

Re: Sigma/Pi bonds

Postby 404536963 » Sun Nov 18, 2018 10:49 pm

Yes I agree there can only be one sigma bond between two atoms in a molecule and two in a pi bond, but in one molecule there can be multiple.

duenezjuleny1D
Posts: 48
Joined: Fri Sep 28, 2018 12:24 am

Re: Sigma/Pi bonds

Postby duenezjuleny1D » Sun Nov 18, 2018 10:57 pm

Sigma bonds are consisted of two orbitals each with one electron, overlap end-to-end with each other. They also allow bound atoms to freely rotate. Pi bonds consist of two orbitals, each with one electron, overlap side-by-side with each other. Pi bonds do not allow bound atoms to rotate. It also matters how how many bonds there are single, double, or triple. All three bonds has a sigma bond and as you increase the number of bonds you add pi bonds.

Sean Reyes 1J
Posts: 67
Joined: Fri Sep 28, 2018 12:24 am

Re: Sigma/Pi bonds

Postby Sean Reyes 1J » Tue Nov 20, 2018 7:02 pm

If you're basing this off a Lewis structure, then finding the amount of sigma and pi bonds is actually not too bad.
Basically, every single bond is counted as a sigma bond, every double bond is counted as both a sigma AND a pi bond, and every triple bond is counted as a sigma bond and TWO pi bonds.
For every bond, there is at least going to be a sigma bond.
For example, in carbon dioxide (CO2), there is a double bond between each oxygen to the carbons. This means that, in total, there are two sigma bonds and two pi bonds.
I hope this helps!!

ran2000
Posts: 66
Joined: Fri Sep 28, 2018 12:15 am

Re: Sigma/Pi bonds

Postby ran2000 » Wed Nov 21, 2018 5:02 pm

Sigma bonds are formed when orbitals overlap head on, along the bond axis. Pi bonds are formed when the ortibals overlap above and below the bond axis.


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