Bond Angle with Lone Pairs

(Polar molecules, Non-polar molecules, etc.)

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Sarah Zhari 1D
Posts: 103
Joined: Sat Sep 14, 2019 12:16 am

Bond Angle with Lone Pairs

Postby Sarah Zhari 1D » Sat Nov 16, 2019 10:13 am

Why are bond angles smaller when there are lone pairs of electrons present? For example, why are the bond angles in a tetrahedral structure larger than the bond angles in a trigonal pyramidal structure?

Jamie Lee 1F
Posts: 106
Joined: Fri Aug 09, 2019 12:16 am

Re: Bond Angle with Lone Pairs

Postby Jamie Lee 1F » Sat Nov 16, 2019 10:21 am

The lone pairs repel the bonded molecules more, thus pushing them together and lessening the bond angles.

Rebekah Alfred 1J
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Joined: Thu Jul 11, 2019 12:15 am
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Re: Bond Angle with Lone Pairs

Postby Rebekah Alfred 1J » Sat Nov 16, 2019 10:29 am

The lone pairs on the central atom influence molecular shape and, thus, affect the bond angles. Specifically, the addition of lone pairs force the bonding electrons closer together, making the bond angles smaller.

cassidysong 1K
Posts: 100
Joined: Fri Aug 30, 2019 12:15 am

Re: Bond Angle with Lone Pairs

Postby cassidysong 1K » Sat Nov 16, 2019 12:12 pm

lone pairs have a greater repelling force, therefore forcing the bonding electrons closer together and therefore decreasing the bond angle slightly


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