Repulsion Strength
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Repulsion Strength
How do you determine which molecules have higher repulsion strengths versus lower repulsion strengths?
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Re: Repulsion Strength
A greater repulsion force typically results from a molecule having a lone pair on the molecule, which increases the repulsion forces between molecules.
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Re: Repulsion Strength
Building on from that, if an atom has more lone pairs, then those lone pairs will push down more on the bonded electrons (resulting in more repulsion strength than an atom with only one lone pair or none).
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Re: Repulsion Strength
Repulsion strength in an increasing order would be bonding-bonding pair, lone-bonding pair, and lone-lone pair. This means that repulsions will be higher if there are lone pairs involved compared to if there were only bonds.
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Re: Repulsion Strength
Bonds in which the atoms have a higher amount of lone pairs results in higher repulsion strength because the electrons are more delocalized and are usually closer to each other, causing stronger repulsions.
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Re: Repulsion Strength
Two lone pairs have the highest repulsion, then a lone pair and bond have the second highest repulsion leaving two bonds to have the lowest repulsion.
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Re: Repulsion Strength
Lone pairs typically have the highest repulsion since there are no electrons being shared, while bonded pairs typically have the lowest repulsion since the electrons are being shared. Therefore, two lone pairs have the highest repulsion, followed by one lone pair, and bond pairs have the least repulsion.
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Re: Repulsion Strength
From one of Dr. Lavelle's lectures, I remember him ranking repulsion strength as so: lone pair-lone pair> lone pair-bonding pair> bonding pair bonding pair.
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Re: Repulsion Strength
From Professor Lavelle's lectures, the order of repulsion strength from least to greatest is bonding-bonding pair, lone-bonding pair, and lone-lone pair.
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