Bond Angles
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Bond Angles
How do you calculate/approximate bond angles in a given molecule? Thanks!
Last edited by JaylinWangDis1L on Sun Nov 22, 2020 5:40 pm, edited 1 time in total.
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Re: Bond Angles
From the knowledge I have gained so far, I believe bond angles are determined experimentally. Bond angles change based on the electron repulsion on the different bonds that are given to us.
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Re: Bond Angles
Hi! I believe you don't need to know how to calculate bond angles. You just need to memorize the general bond angles and be able to determine based on the molecular shape how the bond angle changes. For example, lone pairs decrease the bond angle so for a molecule like H2O, which has 2 lone pairs, the bonding angle would just be less than 109.5 degrees. Hope this helps!
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Re: Bond Angles
JaylinWangDis3D wrote:How do you calculate/approximate bond angles in a given molecule? Thanks!
I believe what you are asking here is for your own individual problem solving, so the best advice I can give is to memorize the bond angles between "parent" shapes as well as memorize that adding lone pairs decreases angle size. So, for example, for a tetrahedral shape, the bond angles are 109.5 degrees. Then, if you add lone pairs, you decrease the angle size, so for this tetrahedral the bond angles would be less than 109.5 degrees (<109.5).
In other words, memorize the angles without lone pairs, and then understand that it decreases as you add lone pairs. Hope this helps!
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Re: Bond Angles
Hi! As far as I know, bond angles are experimentally determined so we don't have to calculate them. You would just have to remember the angles that go with each different shape.
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Re: Bond Angles
As Josh said, the best thing you can do is memorize the parent shapes where all bond angles are equal. After this just problem-solve to see if any bond angles would be larger or smaller do due to more/larger areas of electron density.
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Re: Bond Angles
To reiterate what others have said since bond angles are experimentally determined, I would remember the angles for the parent shapes where all bond angles are equal and then when larger areas of electron density are present then the bond angles would decrease.
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Re: Bond Angles
as others have said, bond angles are experimentally determined so we don't need to calculate them. however, as long as you can remember the shape of a molecule and how the atoms are arranged, you can probably determine an angle by dividing the number of atoms around the central atom by 360
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Re: Bond Angles
You cannot determine bond angles from any molecular structure. You have to search it up because they are experimentally determined, but you can memorize them.
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Re: Bond Angles
Bond angles in specific molecules are calculated experimentally. We can tell by the structure what the approximate bond angles may be. We also know that lone pairs cause more repulsion, so bond angles away from the lone pair may be smaller. We can not determine to what extent they will be smaller, however, that value is derived experimentally.
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Re: Bond Angles
Bond angles are experimentally determined, so you just have to learn what they are for each different shape. I hope this helps!
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Re: Bond Angles
They're experimentally determined, and generally for usage in class, I think we just need to know the bond angles for the generalized shapes, and then make a prediction on what it'll be based on the general shapes.
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Re: Bond Angles
Bond angles can't be calculated but you can approximate how they'll change based on electron repulsion.
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Re: Bond Angles
There's no specific calculation method, but drawing the Lewis structure and determining the number of bonding/nonbonding groups can help determine the geometrical shape and thus the bond angles.
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Re: Bond Angles
It must be experimentally determined. However, Lewis structures and models can help approximate.
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Re: Bond Angles
JoshMoore3D wrote:JaylinWangDis3D wrote:How do you calculate/approximate bond angles in a given molecule? Thanks!
I believe what you are asking here is for your own individual problem solving, so the best advice I can give is to memorize the bond angles between "parent" shapes as well as memorize that adding lone pairs decreases angle size. So, for example, for a tetrahedral shape, the bond angles are 109.5 degrees. Then, if you add lone pairs, you decrease the angle size, so for this tetrahedral the bond angles would be less than 109.5 degrees (<109.5).
In other words, memorize the angles without lone pairs, and then understand that it decreases as you add lone pairs. Hope this helps!
Thank you so much. This really helped me understand how to go about calculating the bond angles in the molecule.
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Re: Bond Angles
You can estimate the bond angle just by measuring. For example, linear is 180, trigonal planar is 120, tetrahedral is 109.5. As everyone else said,the actual bond angle has to be determined experimentally.
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Re: Bond Angles
They are experimentally determined and based off of relative bond angles. That being said, there is no way to calculate out what the bond angle will be. The best way to determine it is to account for the shape and the lone pairs, then make an assumption from there.
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Re: Bond Angles
I dont think you can calculate them. We just know the relative bond angles based on the structure of the molecule.
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Re: Bond Angles
They're experimentally calculated, so I don't think we'll have to know them!! Just the basic ones I believe (e.g. angles of a tetrahedral shape)!
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