Hi everyone!
Whenever a question asks us to determine bond angles, would the bond angles always correspond to the molecular shape? For example, if the molecular shape is linear, the bond angle will always be 180°?
Thank you!
Determining Bond Angles
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Re: Determining Bond Angles
Yup! that's the only way we can determine the bond angle. And in some cases, we are only required to estimate by saying that the bond angle is going to be less than 109.5 degrees, when otherwise we would have to use the internet to find the exact degree.
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Re: Determining Bond Angles
Analyzing the shape will help provide a clear understanding of what the bond angles could possibly be. Directly answering your question, yes, a linear molecular shape has a bond angle of 180 degrees.
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Re: Determining Bond Angles
Hi! Yes you're right, the molecular shapes are used to determine bond angles and you just have to memorize what angles correspond to the shapes.
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Re: Determining Bond Angles
Exactly!
Trigonal bipyramidal = 90
Tetrahedral = 109.5
Trigonal planar = 120
Linear = 180
Interesting to note is that in Sapling, we had to draw a cyclical 3-carbon ring, and since this forms a triangular shape, the bond angle here would be 60 degrees (the sum of the angles in an equilateral triangle is 180, so dividing that across three angles would give a 60 degree angle).
Trigonal bipyramidal = 90
Tetrahedral = 109.5
Trigonal planar = 120
Linear = 180
Interesting to note is that in Sapling, we had to draw a cyclical 3-carbon ring, and since this forms a triangular shape, the bond angle here would be 60 degrees (the sum of the angles in an equilateral triangle is 180, so dividing that across three angles would give a 60 degree angle).
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Re: Determining Bond Angles
That's correct! The molecular shape of the molecule will give you its bond angles.
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Re: Determining Bond Angles
Are lone pairs what make the bond angles "less than (<) 120" and such? And if there are two lone pairs then the bond angel would be less than less than (<<)?
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Re: Determining Bond Angles
Shalyn Kelly 1L wrote:Are lone pairs what make the bond angles "less than (<) 120" and such? And if there are two lone pairs then the bond angel would be less than less than (<<)?
Yes, that is correct, the lone pairs will make the bond angles smaller since they occupy a larger volume of space.
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Re: Determining Bond Angles
Yes! The bond angles are experimentally determined based on molecular shape, so that is how you will determine the bond angle.
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