S- Character of Hybrids
Posted: Tue Nov 20, 2018 8:23 pm
Hi, can anyone help me understand 2F.15 from the 7th Edition.
Question: Noting that the bond angle of a sp^3 hybridized atom is 109.5 degrees and that of an sp^2 hybridized atom is 120 degrees, do you expect the bond angle between two hybrid orbitals to increases or decrease as the s-character of the hybrids is increased?
Answer: As the s-character of a hybrid orbital increase, the bond angle increases.
I do not understand why this is the answer to the question. Can someone please explain.
Question: Noting that the bond angle of a sp^3 hybridized atom is 109.5 degrees and that of an sp^2 hybridized atom is 120 degrees, do you expect the bond angle between two hybrid orbitals to increases or decrease as the s-character of the hybrids is increased?
Answer: As the s-character of a hybrid orbital increase, the bond angle increases.
I do not understand why this is the answer to the question. Can someone please explain.