Problem 4.43


Moderators: Chem_Mod, Chem_Admin

504594108
Posts: 24
Joined: Fri Sep 25, 2015 3:00 am

Problem 4.43

Postby 504594108 » Mon Oct 26, 2015 12:40 pm

What is meant by the s-character of hybrid orbitals? Why does it increase when the bond angle increases?

Harnadar Anand 2F
Posts: 22
Joined: Fri Sep 25, 2015 3:00 am

Re: Problem 4.43

Postby Harnadar Anand 2F » Mon Oct 26, 2015 1:30 pm

The S character can be thought of as the influence that the s orbitals exert on the bond

Sabina Fridman 1D
Posts: 19
Joined: Fri Sep 25, 2015 3:00 am

Re: Problem 4.43

Postby Sabina Fridman 1D » Mon Oct 26, 2015 1:33 pm

Hi, from what I understand s-character relates to how much of the hybrid orbital is made of the s-orbital
like in sp hybridization, s-character is 50% and p-character is 50%, but in sp^3, s-character is 25% where p-character is 75% of the hybridization.
so as bond angle increases, s-character increases because for example in a 180 degree angle the hybridization is likely to be sp so s-character (50%) is higher than that for a hybridization of sp^3 (s-character is 25%) where the bond angle is 109.5 degrees.


Return to “Hybridization”

Who is online

Users browsing this forum: No registered users and 1 guest