exceptions ?


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Karina Rodriguez 2H
Posts: 50
Joined: Wed Sep 30, 2020 9:34 pm

exceptions ?

Postby Karina Rodriguez 2H » Sat Dec 12, 2020 10:02 pm

Are there any exceptions that arise in hybridization? Or will it always depend only on number of bonds?

AndrewNguyen_2H
Posts: 100
Joined: Wed Sep 30, 2020 9:59 pm

Re: exceptions ?

Postby AndrewNguyen_2H » Sat Dec 12, 2020 10:04 pm

To my knowledge there aren't really any exceptions. Be careful when saying number of bonds, as hybridization also include the number of lone pairs. So like oxygen in H2O is really sp3 hybridized.

Madeline Louie 1I
Posts: 56
Joined: Wed Sep 30, 2020 9:48 pm
Been upvoted: 1 time

Re: exceptions ?

Postby Madeline Louie 1I » Sat Dec 12, 2020 10:22 pm

Like Andrew said, the number of regions of electron density equals the number of hybrid orbitals, including both lone pairs and bonding pairs. I also can't think of any exceptions, but always pay attention to the number of sigma bonds, pi bonds, and lone pairs because pi bonds occur through the unhybridized p-orbital.

Kaylee Messick 3J
Posts: 102
Joined: Wed Sep 30, 2020 9:54 pm

Re: exceptions ?

Postby Kaylee Messick 3J » Sat Dec 12, 2020 10:31 pm

Like the others said, the regions of electron density show the number of hybrid orbitals. This would mean that double bonds would still remain one region of electron density. For example, in the lecture on Friday, the example of CO2 had a hybridization of sp even though carbon had double bonds. Hope this helps!

605721741
Posts: 108
Joined: Fri Sep 24, 2021 6:23 am

Re: exceptions ?

Postby 605721741 » Sun Nov 07, 2021 5:27 pm

Cr and Cu are exceptions to the normal aufbau model, because of their 4s1 3d5 and 4s1 3d9 configuration.


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