Hybridization


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Chaleah Duran
Posts: 100
Joined: Fri Sep 24, 2021 5:44 am

Hybridization

Postby Chaleah Duran » Sun Nov 28, 2021 1:52 pm

Why don't pi bonds hybridize?

JacksonWissing2G
Posts: 103
Joined: Fri Sep 24, 2021 5:43 am
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Re: Hybridization

Postby JacksonWissing2G » Sun Nov 28, 2021 2:10 pm

I think it’s just because they have different orientations. Sigma bonds can hybridize since they connect head on, which is necessary for hybridization. Pi bonds overlap laterally though, and because of this different orientation they can’t hybridize.

Somin Lee
Posts: 54
Joined: Fri Sep 24, 2021 6:10 am

Re: Hybridization

Postby Somin Lee » Sun Nov 28, 2021 10:03 pm

pi bond have electron density on each side of internuclear axis. Since they are not connected end to end, the hybridized orbital cannot form pi bond, instead they form sigma bond which have electron density with cylindrical symmetry.

Preethika Praveen 2G
Posts: 100
Joined: Fri Sep 24, 2021 6:25 am

Re: Hybridization

Postby Preethika Praveen 2G » Sun Nov 28, 2021 10:44 pm

Pi bonds do not hybridize because they are formed by the side-to-side overlap of p orbitals whereas sigma bonds connect head-to-head, allowing for hybridization


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