Pi bonds

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Paloma Sanchez 3L
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Joined: Fri Sep 24, 2021 5:45 am

Pi bonds

Postby Paloma Sanchez 3L » Sun Nov 14, 2021 1:02 am

To clarify, pi bonds don't allow bound atoms to rotate because of the overlap of orbitals?

Ayaan_Ekram_2J
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Re: Pi bonds

Postby Ayaan_Ekram_2J » Sun Nov 14, 2021 1:09 am

Hello!

I believe you are correct. Pi bonds will not allow for rotation because there are two parallel overlaps of the orbitals, making rotation impossible. I hope this helps!

Jennifer Huynh 3I
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Joined: Fri Sep 24, 2021 5:04 am

Re: Pi bonds

Postby Jennifer Huynh 3I » Sun Nov 14, 2021 1:10 am

In pi bonds, electrons overlap both above and below the atoms bonded together, preventing the rotation of the molecule about the double bond. If rotation does occur, the pi bond would break.
CH02_F_F04.png

Nandini_Parmar_1I
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Re: Pi bonds

Postby Nandini_Parmar_1I » Sun Nov 14, 2021 3:32 pm

Pi bonds don't allow rotation to occur, so yes you are right because the overlap of orbitals is a pi bond so it cannot rotate. Pi bond breaks if rotation happens.

Vanessa Wiratmo 3k
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Re: Pi bonds

Postby Vanessa Wiratmo 3k » Sun Nov 14, 2021 8:30 pm

yes, that is correct. Pi bonds have two lobes that overlap with two lobes of an orbital of the other atom. It's a lateral overlap, so this prevents pi bonds from rotating because it would break.

Triston Dinh 1D
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Joined: Fri Sep 24, 2021 6:03 am

Re: Pi bonds

Postby Triston Dinh 1D » Tue Nov 16, 2021 10:52 am

Yes, pi bonds do not allow for rotation because it is a lateral overlap from above and below the atom. If rotation was attempted, the pi bond would break. On the other hand, sigma bonds are a result of the head-to-head overlapping of the orbitals and thus do allow for rotation.

Genelle Marcelino-Searles 2G
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Re: Pi bonds

Postby Genelle Marcelino-Searles 2G » Tue Nov 16, 2021 10:56 am

Yes! Pi bonds overlap side by side, rather than end to end, which doesn't allow the atoms to rotate.

Jordyn Lee 1J
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Re: Pi bonds

Postby Jordyn Lee 1J » Tue Nov 16, 2021 11:35 am

Hi, you are correct that pi bonds do not allow bound atoms to rotate because the orbitals overlap side-by-side.

LukeYing_3H
Posts: 103
Joined: Fri Sep 24, 2021 6:16 am

Re: Pi bonds

Postby LukeYing_3H » Fri Nov 19, 2021 11:01 pm

I believe you are correct, pi bonds do not allow for rotation because the orbitals overlap side-by-side

Rebecca Preusch 2C
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Joined: Fri Sep 24, 2021 6:26 am

Re: Pi bonds

Postby Rebecca Preusch 2C » Sat Nov 20, 2021 8:16 pm

You are correct. If the bound atoms were to rotate, the pi bond would break.

SheaZenker_3F
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Re: Pi bonds

Postby SheaZenker_3F » Sat Nov 20, 2021 9:20 pm

You are correct, sigma bonds allow atoms to rotate though

Aashna Sibal 2F
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Joined: Fri Sep 24, 2021 5:10 am

Re: Pi bonds

Postby Aashna Sibal 2F » Sat Nov 20, 2021 10:05 pm

Yup, pi bonds do not allow atoms to rotate, but sigma bonds do. This is because in pi bonds, orbitals overlap. Therefore, if the atoms were to rotate, the orbital would not overlap and then the bond would be broken.

Ellen Tsai 3D
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Joined: Fri Sep 24, 2021 5:55 am

Re: Pi bonds

Postby Ellen Tsai 3D » Sun Nov 21, 2021 1:46 pm

Yes! If they were allowed to rotate then the pi bonds would simply break

Olivia Ghorai 1J
Posts: 53
Joined: Fri Sep 24, 2021 7:35 am

Re: Pi bonds

Postby Olivia Ghorai 1J » Sun Nov 21, 2021 2:02 pm

Yes, pi bonds restrict rotation because of the two orbitals that overlap. If the bonded atoms were to rotate, the pi bond would break

505734174
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Re: Pi bonds

Postby 505734174 » Sun Nov 21, 2021 2:14 pm

Yes, pi bonds have two areas of electron sharing on opposite sides of the electron cloud therefore, it locks the bond in place and prevents rotation.

Narin Maisha 2H
Posts: 100
Joined: Fri Sep 24, 2021 6:49 am

Re: Pi bonds

Postby Narin Maisha 2H » Wed Dec 01, 2021 2:51 pm

Pi bonds jeep from rotation because they overlap in two different area, and any type of rotation would result in breaking the pi bond. On the other hand sigma bonds can rotate due to only overlapping in one area.

madelyn kelly 1I
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Joined: Fri Sep 24, 2021 6:24 am

Re: Pi bonds

Postby madelyn kelly 1I » Wed Dec 01, 2021 2:59 pm

Yes, pi bonds would not be able to rotate because they overlap in 2 locations, so the pi bond would break by trying to rotate.

Alejandro Oliva 2F
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Joined: Fri Sep 24, 2021 5:39 am

Re: Pi bonds

Postby Alejandro Oliva 2F » Wed Dec 01, 2021 6:19 pm

Yes, pi bonds have overlapping orbital which do not allow for rotation of the molecule. On the other hand, sigma bonds allow for this rotation to occur.

905740390
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Joined: Fri Sep 24, 2021 7:31 am

Re: Pi bonds

Postby 905740390 » Sun Dec 05, 2021 11:41 am

pi bonds restrict so there can be no movement because of the orientation of the bonds

Aashna Sibal 2F
Posts: 55
Joined: Fri Sep 24, 2021 5:10 am

Re: Pi bonds

Postby Aashna Sibal 2F » Sun Dec 05, 2021 4:19 pm

Yup, pi bonds are the parallel overlap of orbitals. Therefore, if one rotates, they would no longer be parallel in the plane, breaking the pi bond.

Olivia Ghorai 1J
Posts: 53
Joined: Fri Sep 24, 2021 7:35 am

Re: Pi bonds

Postby Olivia Ghorai 1J » Mon Dec 06, 2021 11:26 pm

Yes you are correct, pi bonds do not allow rotation. If the molecule were to rotate, the pi bonds would break.


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