Behavior of pi bonds

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Spencer T
Posts: 71
Joined: Fri Sep 29, 2023 11:14 am

Behavior of pi bonds

Postby Spencer T » Mon Dec 04, 2023 1:03 am

When determining the number of pi bonds on question 15 of the Molecular Shape assignment, why does the triple bond contain 2 pi bonds, while the double bond only contains one pi bond? Is there a reason the triple bond contains 2 pi bonds instead of just one bond?

Thanks for the help.

Patrick Blankenberg
Posts: 134
Joined: Fri Sep 29, 2023 11:08 am

Re: Behavior of pi bonds

Postby Patrick Blankenberg » Mon Dec 04, 2023 1:48 am

This is because a single bond is always a sigma bond. This is because when you think of the p-orbitals, only one orbital can overlap, as the other orbitals will be out of phase. These other orbitals lining up side by side make these pi bonds.

For simplicity,

Single bond --> always 1 sigma bond
Double bond --> 1 sigma bond + 1 pi bond (i believe there may be an exception of two but idk if thats in the scope of this class)
Triple bond --> 1 sigma bond + 2 pi bond


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