Ionization Energy

Moderators: Chem_Mod, Chem_Admin

Katrina Jang 2H
Posts: 21
Joined: Fri Sep 25, 2015 3:00 am

Ionization Energy

Postby Katrina Jang 2H » Sat Oct 31, 2015 12:06 pm

Why would a species have a lower ionization energy when the electron is lost from a higher molecular orbital?

Jonathan Shih 3H
Posts: 37
Joined: Fri Sep 25, 2015 3:00 am

Re: Ionization Energy

Postby Jonathan Shih 3H » Sun Nov 01, 2015 1:59 am

If you think of this answer in terms of the atomic diagram, the the further away the electron is from the nucleus, the easier it is to remove it from the atom. Therefore, when it is in a higher molecular orbital, it is farther from the positive nucleus (repelled further by the electrons other than the one getting pulled away (the electrons in between)), so it requires less energy to remove. Thus, the lower ionization energy. Hope this helps! Try picturing it if this descrption isn't necessarily doing it for you!

Return to “*Molecular Orbital Theory (Bond Order, Diamagnetism, Paramagnetism)”

Who is online

Users browsing this forum: No registered users and 1 guest