Unpaired Electron Placement in Radicals

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Serene Liu 3H
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Unpaired Electron Placement in Radicals

Postby Serene Liu 3H » Mon Nov 29, 2021 5:09 pm

Textbook problem 2.61 asks you to draw the Lewis structure of HOCO, which is a radical. How do you know which element the unpaired electron goes on?

505766240
Posts: 100
Joined: Fri Sep 24, 2021 7:08 am

Re: Unpaired Electron Placement in Radicals

Postby 505766240 » Tue Nov 30, 2021 11:57 am

When you draw the lewis structure for HOCO, I believe the valence electrons for the two oxygens and one hydrogen should be filled already, so you only have C left to put the unpaired electron on.

Sujin Lim 1H
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Re: Unpaired Electron Placement in Radicals

Postby Sujin Lim 1H » Tue Nov 30, 2021 12:33 pm

I think it was mentioned during one of my discussion sections that the unpaired electron for the radical should go on the less electronegative atom of the molecule (H atoms excluded). This is because the more electronegative atom will want to have more valence electrons, so they should have the paired electrons, whereas the less electronegative should have the unpaired (one less) electron. Hope this is correct!


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