Achieve #1

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Aliza Hacking 1A
Posts: 100
Joined: Fri Sep 24, 2021 5:39 am

Achieve #1

Postby Aliza Hacking 1A » Sat Nov 27, 2021 9:40 pm

hi! could someone just quickly clarify why the end of [Co(NH3)5Cl]Cl2 isn't dichloride/ when that prefix would and wouldn't be used ? I think we used it in class for when there were 2 water molecules outside the brackets. thank you!

Ayaan_Ekram_2J
Posts: 165
Joined: Fri Sep 24, 2021 5:39 am

Re: Achieve #1

Postby Ayaan_Ekram_2J » Sat Nov 27, 2021 10:05 pm

Hello!

I believe the reason for this is because Cl is not inside of the bracket, so it is not a ligand. Therefore, I believe it does not take a prefix as it is not a ligand but instead forms a bond with the positively charged portion of the coordination compound within the brackets. I hope this helps!

WendyN_L2
Posts: 100
Joined: Fri Sep 24, 2021 5:47 am

Re: Achieve #1

Postby WendyN_L2 » Sat Nov 27, 2021 10:24 pm

For anions outside the coordination sphere/bracket you would just use the normal anion name, but for specifically water that's when you add the greek prefixes. Hope this helps

205686400
Posts: 69
Joined: Fri Sep 24, 2021 5:44 am

Re: Achieve #1

Postby 205686400 » Sat Nov 27, 2021 11:14 pm

Hi! This is because the Cl2 is outside of the coordination complex and therefore is just used as a way to counter act the overall oxidation state of the complex itself.

Caitlin_Tang_Dis3H
Posts: 109
Joined: Fri Sep 24, 2021 7:03 am

Re: Achieve #1

Postby Caitlin_Tang_Dis3H » Sat Nov 27, 2021 11:56 pm

Based on the naming guidelines for ligands we should follow this order.
1. greek prefix
2. Ligand Name
3. Transition Metal
4. Oxidation state
5. Ions/atoms/molecules outside of the brackets


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