Oxalate and CO3 2- as a polydentate
Moderators: Chem_Mod, Chem_Admin
-
- Posts: 47
- Joined: Sat Aug 17, 2019 12:15 am
Oxalate and CO3 2- as a polydentate
As I was solving 9C.5, I did not get b) and d). For b, can someone explain how one molecule can either be a mono- or bidentate ligand? For d), since there are four Oxygen molecules with lone pairs, shouldn't it be a tetradentate ligand? Thank you for your help!
-
- Posts: 106
- Joined: Fri Aug 30, 2019 12:15 am
Re: Oxalate and CO3 2- as a polydentate
For d), oxalate is bidentate as there will be two double bonds (these won't bind to the metal as the pi bonds restrict rotation, thus only 2 of the single bonded oxygens can bind at once).
-
- Posts: 100
- Joined: Sat Aug 17, 2019 12:16 am
- Been upvoted: 2 times
Re: Oxalate and CO3 2- as a polydentate
Would it always be the two single bonded oxygens that bond to the central atom? Could it be one of the double bonded oxygens and one of the single bonded ones?
Re: Oxalate and CO3 2- as a polydentate
I think it would always be the single bonded ones due to the absense of the pi bond but I am not too sure
Return to “Shape, Structure, Coordination Number, Ligands”
Who is online
Users browsing this forum: Google [Bot] and 5 guests