Textbook Problem 9C7

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IsabelMurillo3K
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Joined: Wed Sep 30, 2020 9:51 pm

Textbook Problem 9C7

Postby IsabelMurillo3K » Sun Dec 06, 2020 8:51 pm

Hey guys!
I was wondering if anyone could explain how we can determine which structures can form chelating complexes? I have come across this term a couple of times in different problems regarding ligands, however, I am confused as to what this term means, or how I can apply it in problems. Thanks in advance!

Xinyu Li 1C
Posts: 101
Joined: Wed Sep 30, 2020 9:36 pm

Re: Textbook Problem 9C7

Postby Xinyu Li 1C » Sun Dec 06, 2020 8:58 pm

Chelating complexes are complexes containing a ligand that forms a ring of atoms that includes the central metal atom. In order to form a chelate, you need a ligand with the ideal geometry, which is (atom w/ lone pair) + (spacer) + (spacer) + (atom w/ lone pair) and the bonds need to be able to rotate (single bonds).

Image
N is the atom providing the lone pair and C is spacer ^


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