Week 9 Achieve question 5

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Xinyue Zou 2K
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Joined: Fri Sep 24, 2021 7:12 am

Week 9 Achieve question 5

Postby Xinyue Zou 2K » Fri Nov 26, 2021 4:07 pm

For [Pt(en)Cl2] how would you find the coordination number of Pt? I don't understand what (en) is supposed to represent and that's tripping me up.

Crystal Ma 2J
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Re: Week 9 Achieve question 5

Postby Crystal Ma 2J » Fri Nov 26, 2021 5:46 pm

en represents Ethylenediamine or C₂H₄(NH₂)₂

Ainsley McCabe 2D
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Re: Week 9 Achieve question 5

Postby Ainsley McCabe 2D » Fri Nov 26, 2021 5:49 pm

Are we supposed to know what en represents on the final or will we be given that formula?

Janice Hu 2L
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Re: Week 9 Achieve question 5

Postby Janice Hu 2L » Fri Nov 26, 2021 5:51 pm

(en) is the abbreviation for ethylenediamine when its a ligand. As for figuring out the coordination number, just remember that (en) is bidentate and Cl- is monodentate :)

Jennifer Huynh 3I
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Joined: Fri Sep 24, 2021 5:04 am

Re: Week 9 Achieve question 5

Postby Jennifer Huynh 3I » Fri Nov 26, 2021 5:54 pm

En is ethylenediamine, which is a bidentate that bonds to the metal at two positions. Two N atoms in en bind to the metal. Cl is a monodentate ligand that binds to the metal in one position.
coordination # = 2 + 2 = 4

Janice Hu 2L
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Re: Week 9 Achieve question 5

Postby Janice Hu 2L » Fri Nov 26, 2021 5:55 pm

Ainsley McCabe 2E wrote:Are we supposed to know what en represents on the final or will we be given that formula?

I think it would be safe to know it since Dr. Lavelle talked about it in one of his lectures.

Heba Bounar 3K
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Re: Week 9 Achieve question 5

Postby Heba Bounar 3K » Fri Nov 26, 2021 7:46 pm

Hi! en is a bidentate ligand, meaning it binds to the transition metal at two locations. Cl is a monodentate ligand, meaning it binds to the transition metal in one location. Therefore, if you add up the total of binding locations, the coordination number of Pt is equal to 2 (from the en) + 2 (from the chlorines) = 4. Hope that helps!


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