Brackets and Coordination Number

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Aliza Hacking 1A
Posts: 100
Joined: Fri Sep 24, 2021 5:39 am

Brackets and Coordination Number

Postby Aliza Hacking 1A » Sat Nov 27, 2021 9:22 pm

Hi! straight forward question but when determining the coordination number of a compound, do you always ignore the atom(s) outside the brackets when counting ligands, or are there cases when the atoms outside the bracket affect the coordination number? thank you!

LouiseLin2L
Posts: 100
Joined: Fri Sep 24, 2021 6:27 am

Re: Brackets and Coordination Number

Postby LouiseLin2L » Sat Nov 27, 2021 9:29 pm

I think only atoms inside the brackets would count towards the coordination number since they are the ligands that are directly bonded to the central atom.

Holly Do 2J
Posts: 104
Joined: Fri Sep 24, 2021 5:11 am

Re: Brackets and Coordination Number

Postby Holly Do 2J » Sat Nov 27, 2021 10:34 pm

Yes you would ignore anything outside the brackets and just focus on everything inside since those are the ligands directly attached to the central atom.

Anish_Marripati_2F
Posts: 104
Joined: Fri Sep 24, 2021 7:31 am

Re: Brackets and Coordination Number

Postby Anish_Marripati_2F » Sat Nov 27, 2021 11:09 pm

You wouldn't pay attention to the numbers outside the brackets. This is because inside the bracket the ligands are directly attached to the central atom, and from there you're allowed to determine the coordination number.

Alex FreeWolf 2E
Posts: 107
Joined: Fri Sep 24, 2021 6:04 am

Re: Brackets and Coordination Number

Postby Alex FreeWolf 2E » Sat Nov 27, 2021 11:15 pm

Only the compounds/atoms within the brackets are accounted for in the coordination # as they are directly bonded to central atom

Jessica Cornelia Hongarta 1G
Posts: 114
Joined: Fri Sep 24, 2021 5:49 am

Re: Brackets and Coordination Number

Postby Jessica Cornelia Hongarta 1G » Sun Nov 28, 2021 12:20 am

Hi! Yes, so the coordination number here refers to the number of ligands that are attached to the central metal atom. So, you should only focus on what is inside the bracket.

205686400
Posts: 69
Joined: Fri Sep 24, 2021 5:44 am

Re: Brackets and Coordination Number

Postby 205686400 » Sun Nov 28, 2021 12:32 am

Hi! If you were looking at the coordination number itself, then it is safe to say that you may disregard anything outside of the brackets. The only time you should consider anything outside of the brackets is when determining oxidation states.

Sanskriti Balaji 1J
Posts: 52
Joined: Fri Sep 24, 2021 6:28 am

Re: Brackets and Coordination Number

Postby Sanskriti Balaji 1J » Sun Nov 28, 2021 12:51 am

Hi! To figure out the coordination number, you only need to worry about the atoms inside the brackets! You can disregard the atoms outside of the brackets!

Kiana Rogers 1E
Posts: 109
Joined: Fri Sep 24, 2021 5:15 am

Re: Brackets and Coordination Number

Postby Kiana Rogers 1E » Sun Nov 28, 2021 1:25 am

I believe when determining the coordination number, you ignore everything outside the brackets.

madeleinewright
Posts: 54
Joined: Fri Sep 24, 2021 5:36 am

Re: Brackets and Coordination Number

Postby madeleinewright » Sun Nov 28, 2021 12:05 pm

Yes, when determining coordination number you only look at the atoms inside the brackets.

michaelcrisera
Posts: 50
Joined: Fri Sep 24, 2021 6:23 am

Re: Brackets and Coordination Number

Postby michaelcrisera » Sun Nov 28, 2021 12:23 pm

Yes, when determining the coordination number of a compound, only the elements inside the brackets are considered. The number of nonmetal elements inside of the brackets corresponds to the number of ligands that are bound to the central metal atom.

Santiago Chang 2K
Posts: 54
Joined: Fri Sep 24, 2021 6:55 am

Re: Brackets and Coordination Number

Postby Santiago Chang 2K » Sun Nov 28, 2021 12:25 pm

Only atoms inside the brackets count for the coordination number, so you can ignore the rest. Hope this helps!

205705413
Posts: 99
Joined: Fri Sep 24, 2021 5:46 am

Re: Brackets and Coordination Number

Postby 205705413 » Sun Nov 28, 2021 1:41 pm

The ligands inside of the bracket only contribute to the coordination number.

Lauren Wasef 3C
Posts: 102
Joined: Fri Sep 24, 2021 5:29 am

Re: Brackets and Coordination Number

Postby Lauren Wasef 3C » Sun Nov 28, 2021 2:02 pm

Yes when trying to find the coordination number ignore all the atoms outside the brackets.
Ex: K3 [CoF6] has a coordination number of 6 because we ignored the K3 outside the brackets.


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