Question 3 on the Homework for Week 9

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Sydney Rohan 3G
Posts: 107
Joined: Fri Sep 24, 2021 5:58 am

Question 3 on the Homework for Week 9

Postby Sydney Rohan 3G » Sun Nov 28, 2021 10:16 pm

I am confused about question 3 on the homework. The question state:

Which geometry or geometries are common for complexes with a coordination number of 4?
a) tetrahedral
b) seesaw
c) square planar
d) trigonal bipyramidal

I figured out that tetrahedral would be one of the answers, but I can not figure out which other answer is correct. Can someone please help?

305597516
Posts: 101
Joined: Fri Sep 24, 2021 7:17 am

Re: Question 3 on the Homework for Week 9

Postby 305597516 » Sun Nov 28, 2021 10:19 pm

In the lecture, the professor said that 4 ligands could mean either tetrahedral or square planar, but you are not expected to know which is which (when seeing just a formula I think). So I think the other answer would be square planar. I think seesaw is a possible structure, but is just not common like we see with square planar and tetrahedral, so we would not consider it in this answer.
Last edited by 305597516 on Sun Nov 28, 2021 10:21 pm, edited 1 time in total.

Nithya Madhu 2L
Posts: 100
Joined: Fri Sep 24, 2021 6:28 am

Re: Question 3 on the Homework for Week 9

Postby Nithya Madhu 2L » Sun Nov 28, 2021 10:20 pm

Hey,
Basically for coordination number we are only looking the number of bonds to the central atom, not the lone pairs.
Since tetrahedral and square planar have 4 bonds to the central atom, they have a coordination number or 4.
And even though square planar has 2 lone pairs, this does not matter for the coordination number since we are only looking at the bonded atoms/molecules to the central atom.
Hope that helps!


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