coordination number

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mya warner 2C
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coordination number

Postby mya warner 2C » Wed Dec 01, 2021 12:11 am

I'm still having some trouble understanding how to find the coordination number of a molecular compound, like the second exercise on Week 9 HW. Would someone please explain their process that they go through to find the coordination numbers?

Jaipal Virdi 2I
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Re: coordination number

Postby Jaipal Virdi 2I » Wed Dec 01, 2021 12:53 am

In the context of our class, the coordination number refers to how many different ligands are bonded (total number of donor atoms) to the central metal species/complex. For example [M(NH3)3] would have a coordination number of 3 since there are three monodentate (NH3) ligands being bonded. Remember anything outside of the brackets or coordination sphere is not included. I hope this helps!

405825570
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Re: coordination number

Postby 405825570 » Wed Dec 01, 2021 1:57 am

Could someone maybe explain what a coordination sphere is and why it is significant? thank you

Meghan Spoeri 2D
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Re: coordination number

Postby Meghan Spoeri 2D » Wed Dec 01, 2021 9:27 am

hi! A coordination sphere of a coordination complex is made up of the central metal atom and its attached ligands.

Nancy_La_1H
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Re: coordination number

Postby Nancy_La_1H » Wed Dec 01, 2021 11:16 am

Coordination Number is just the number of ligand bonded to the central atom(usually a TM). Only count the ligands that are inside the brackets. When there are parentheses, count the subscript of the parentheses not the molecule inside of it.

mya warner 2C
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Re: coordination number

Postby mya warner 2C » Wed Dec 01, 2021 1:21 pm

As a follow up, how does the charge of the overall compound, the number outside of the brackets such as [Ni(CN)4]^2- , affect the coordination compound, if at all?

Ivy Vo Dis 1C
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Re: coordination number

Postby Ivy Vo Dis 1C » Wed Dec 01, 2021 1:26 pm

A coordination number is the total number of ligands that are bonded to a central metal cation. When counting to find the coordination number, we only recognize what is within the coordination sphere (what is within the brackets). The coordination number would be the subscript of the ligand compound.

Caitlyn Lo 2F
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Re: coordination number

Postby Caitlyn Lo 2F » Wed Dec 01, 2021 7:10 pm

The coordination number is the number of ligands bonded to the central metal atom

Gavin Trent 2F
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Re: coordination number

Postby Gavin Trent 2F » Thu Dec 02, 2021 3:19 pm

The coordination number of a compound is just the total number of bonds between the central metal cation and its ligands. One tip is that (en) is bidentate, meaning it adds 2 to the coordination number, and (edta) is hexadentate, meaning it adds six.

Adithi Ayyala 2G
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Re: coordination number

Postby Adithi Ayyala 2G » Thu Dec 02, 2021 8:12 pm

Hi!
The coordination number just refers to the number of ligands bonded to the central transition metal. As a result, when given the chemical formula for a coordination compound, just count up how many ligands are in the coordination sphere, and when given the diagram of it, just count how many individual ligands are bonded to the central metal.
Hope this helps!


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