H2O vs C2O4 2-

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rita_h
Posts: 122
Joined: Fri Sep 24, 2021 5:48 am

H2O vs C2O4 2-

Postby rita_h » Wed Dec 01, 2021 10:29 pm

H2O is said to have a ligand that is monodentate (1 site to pair with a metal at the level of the oxygen atom due to presence of the lone pair).
In C2O4 2-, yes the two negative oxygens make up sites for metal bonding therefore serving as ligands- but why don't the lone pairs on the oxygen atoms (that are double bonded to carbon) also serve as ligands?

Natalie Keung 1D
Posts: 138
Joined: Fri Sep 24, 2021 5:47 am
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Re: H2O vs C2O4 2-

Postby Natalie Keung 1D » Thu Dec 02, 2021 9:12 am

I don't know if this is the proper way to view this, but it has worked for me so far. Whenever there are polydentate ligands, I always look for either lone pairs on the N atoms of lone pairs on O with a -1 charge.


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