Chelating

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Kati Rady-Pentek 1E
Posts: 51
Joined: Fri Sep 24, 2021 6:42 am

Chelating

Postby Kati Rady-Pentek 1E » Sun Dec 05, 2021 1:30 am

How do you know if a ligand will chelate with the metal?

105605391
Posts: 125
Joined: Fri Sep 24, 2021 6:30 am
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Re: Chelating

Postby 105605391 » Sun Dec 05, 2021 11:37 am

Ligands need two or more points (Bidentante or more) to bind to the central TM to form a chelating complex.

Darren Apostol 2L
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Re: Chelating

Postby Darren Apostol 2L » Sun Dec 05, 2021 11:47 am

As said, if there's a ligand that bonds to the central metal at two or more points, the compound is a chelate. An example is en or ethylenediamine which is bidentate (the two nitrogens have lone pairs).

Shania Garrison Discussion 3E
Posts: 149
Joined: Wed Feb 17, 2021 12:24 am

Re: Chelating

Postby Shania Garrison Discussion 3E » Sun Dec 05, 2021 11:54 am

helating happens when you you have a polydentate ligand. Chelating means that it must form a ring around the transition metal. This can be on big molecule like a hexadentate one, or something like 2 bidentate molecules

Mahika Saoji 3K
Posts: 100
Joined: Fri Sep 24, 2021 6:20 am

Re: Chelating

Postby Mahika Saoji 3K » Sun Dec 05, 2021 12:20 pm

Hi! A chelate by definition is a ligand that is bonded to a central metal atom at two or more points. Chelating usually occurs when you have a polydentate ligand. I hope that helped!

Macy_Anderson_2F
Posts: 100
Joined: Fri Sep 24, 2021 5:02 am

Re: Chelating

Postby Macy_Anderson_2F » Sun Dec 05, 2021 12:49 pm

In lecture, professor said that a simple rule is if there is an atom with an atom with a lone pair bound to a spacer that is bound to another spacer that is bound you an atom with a lone pair you can have a chelate. Simply: Atom with a lone pair--spacer--spacer--atom with a lone pair, where the -- are bonds and the spacers are atoms (like C).


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