Ka vs pKa

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305561744
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Ka vs pKa

Postby 305561744 » Sun Jan 16, 2022 11:40 pm

Can someone explain the differences between these two for acid base reactions? Which one involves taking the log?

Sohan Talluri 1L
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Re: Ka vs pKa

Postby Sohan Talluri 1L » Sun Jan 16, 2022 11:45 pm

KA is the equilibrium constant for the acid and is calculated by KA = [H+][A-] / [HA]. pKA refers to the "power of KA" and is calculated by pKA = -log10 (KA).

Hopefully this helps and please correct me if there are any mistakes.

Sunny Hou 2I
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Re: Ka vs pKa

Postby Sunny Hou 2I » Sun Jan 16, 2022 11:50 pm

Hi,
So the difference between Ka and pKa is that Ka is the dissociation constant for acid and represents the strength of the acid, whereas pKa is the -log of the Ka value. These two are inversely related, so the larger the Ka, the smaller the pKa and thus the stronger the acid is. This is the same principle for bases as well, with Kb and pKb. I remember it as p=-log, for ease of understanding.

Hope this helps.

Natalie Swerdlow 3K
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Re: Ka vs pKa

Postby Natalie Swerdlow 3K » Sun Jan 16, 2022 11:56 pm

If you're trying to classify an acid from Ka and pKa, the higher the Ka value, the stronger the acid. Therefore, the lower the pKa value, the stronger the acid as well. This is the same with Kb and pKb for bases as well.

oliviahelou
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Re: Ka vs pKa

Postby oliviahelou » Mon Jan 17, 2022 7:12 am

Ka: a strong acid has a high Ka value and a weak acid will have a lower Ka value.
pKa: it is kind of the opposite, the lower the pKa value, the stronger the acid.

Logically, it would be the same for the kb and pKb values for bases

Hannah_Pon_1F
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Re: Ka vs pKa

Postby Hannah_Pon_1F » Mon Jan 17, 2022 11:09 am

pKa is the -log(Ka). One of the reasons we use pka is to compare this value directly to the pH. This tells you if there are more charged or neutral species present.

Coraly De Leon
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Re: Ka vs pKa

Postby Coraly De Leon » Mon Jan 17, 2022 1:19 pm

Hello,
Just as my peers mentioned,
Ka will be the disassociation acid constant that will represent the strength of the acid whereas pKa is the -log of Ka. They both have an inverse relationship: the larger the Ka, the smaller the pKa value.

elletruchan2I
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Re: Ka vs pKa

Postby elletruchan2I » Mon Jan 17, 2022 1:47 pm

When a p is attached to something, it always means that the negative log is being taken of that number. Other than this, both Ka and pKa convey the same information of how strong an acid is, but a strong acid will be smaller for pKa and larger for Ka.

Wilson Zheng 1L
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Re: Ka vs pKa

Postby Wilson Zheng 1L » Mon Jan 17, 2022 1:49 pm

Ka is the equilibrium constant for acids! pKa is the -log value of Ka. A lower pKa equates to a higher Ka, and the higher the Ka, the stronger the acid!

Madison Nguyen 3L
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Re: Ka vs pKa

Postby Madison Nguyen 3L » Mon Jan 17, 2022 2:32 pm

Ka is simply the negative antilog of the pKa as the dissociation acid constant, whereas pKa is the negative log of the Ka.

Hailey Sarmiento 3E
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Re: Ka vs pKa

Postby Hailey Sarmiento 3E » Mon Jan 17, 2022 2:41 pm

Ka is the equilibrium constant for an acid reaction (Kb is the same but for a base reaction) and the pKa is the negative log of the Ka (pKa = -log(Ka)). i like to think of this relationship as similar to the relationship between pH and [H3O+] or pOH and [OH-]

Srikar_Chintala_1E
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Re: Ka vs pKa

Postby Srikar_Chintala_1E » Mon Jan 17, 2022 2:51 pm

Ka is the equilibrium constant for the acid which you would set up as a fraction. However, pKa is the -log of the Ka value.

Natasha
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Re: Ka vs pKa

Postby Natasha » Mon Jan 17, 2022 6:32 pm

Ka is representative of the disassociation constant which is representative of the strength. On the other hand pka is the -log of Ka and there is an inverse relationship between Ka and pKa.

Amanda Tran 1D
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Re: Ka vs pKa

Postby Amanda Tran 1D » Mon Jan 17, 2022 6:41 pm

Generally speaking, "p" implies the -log of something. Ka is the equilibrium/dissociation constant of an acid, so pKa = -log (Ka).

sadiebrebes
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Re: Ka vs pKa

Postby sadiebrebes » Mon Jan 17, 2022 6:45 pm

305561744 wrote:Can someone explain the differences between these two for acid base reactions? Which one involves taking the log?


Hello, as mentioned before, the Ka is the equilibrium constant, where the pKa is the negative log of the Ka. They are inversely proportional, when one goes up the other goes down. The higher the Ka the Stronger the acid and the smaller the Pka the stronger the acid. The higher the Ka, the more the acid dissociates.

Joseph Lee
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Re: Ka vs pKa

Postby Joseph Lee » Mon Jan 17, 2022 7:27 pm

Ka is the actual constant and pKA is the negative log of that

Diana Avalos
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Re: Ka vs pKa

Postby Diana Avalos » Tue Jan 18, 2022 9:59 am

Ka is the equilibrium canstant, its Kb for the base, and pKa is the -log of pKa, and pKb is the negative log of Kb


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