K=1

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Aaron Akhavan-Dis1B
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Joined: Wed Sep 30, 2020 9:59 pm

K=1

Postby Aaron Akhavan-Dis1B » Sun Jan 10, 2021 5:29 pm

I remember in the lecture that Dr. Lavelle said K=1 was rare. Why is it rare? I get that it means that neither R or P is favored since it is in the range of 10^-3 and 10^3. But why is that specific value rare? Might not be important but I'm curious

Sahiti Annadata 3D
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Joined: Wed Sep 30, 2020 10:01 pm

Re: K=1

Postby Sahiti Annadata 3D » Sun Jan 10, 2021 5:40 pm

I think K=1 is specifically rare because this means that the concentration of reactants and of products are equal at equilibrium, so no change is happening in the concentrations of the species. This is what makes K=1 so different.

Rich Luong 1D
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Joined: Wed Sep 30, 2020 9:49 pm

Re: K=1

Postby Rich Luong 1D » Sun Jan 10, 2021 5:53 pm

K = 1 implies that the reactants and products basically have the same concentration/pressure. I think this is a rare case because most scenarios have reactants and products produce different values so to get them to be exactly the same is very unlikely.

Jonathan Malau 1F
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Joined: Wed Sep 30, 2020 9:31 pm

Re: K=1

Postby Jonathan Malau 1F » Sun Jan 10, 2021 5:56 pm

If the equilibrium constant is 1 or nearly 1, it means that the molarities of the reactants and products are about the same. It's simply rare to see that no change is occurring at that point.

Jalaia Jackson 2G
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Joined: Wed Sep 30, 2020 9:45 pm

Re: K=1

Postby Jalaia Jackson 2G » Sun Jan 10, 2021 6:14 pm

Agreeing with what everyone else said, having both the products and reactants with equal concentrations at equilibrium is very difficult to produce. That’s probably why lavelle mentioned that.

Megan Lu 3D
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Joined: Wed Sep 30, 2020 9:49 pm

Re: K=1

Postby Megan Lu 3D » Sun Jan 10, 2021 6:19 pm

Hi! Like others have mentioned above, when the equilibrium constant is 1, the concentration/pressure of the products and reactants will be equal. To my understanding, this just happens to be rare because there is usually a tendency for reactions to favor one direction over another.

rhettfarmer-3H
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Re: K=1

Postby rhettfarmer-3H » Sun Jan 10, 2021 6:47 pm

K=1 means that reactants and products literally have the same concentration. Lavalle describes this as rare because think about how rare that has to be that they are perfectly the same, and in terms of the reaction, it is hard for the reaction to flow and create a product or vice versa. Also, means it basically equilibrium and flowing at a constant rate of both the reaction and reverse.

Maddie Turk Disc 2J
Posts: 90
Joined: Wed Sep 30, 2020 9:48 pm

Re: K=1

Postby Maddie Turk Disc 2J » Sun Jan 10, 2021 6:59 pm

I think it is rare because it means that the reaction neither favors the products or reactants and they are completely equal in concentration which is hard to find.

JoshMoore2B
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Joined: Wed Sep 30, 2020 9:51 pm

Re: K=1

Postby JoshMoore2B » Sun Jan 10, 2021 9:28 pm

Aaron Akhavan-Dis1B wrote:I remember in the lecture that Dr. Lavelle said K=1 was rare. Why is it rare? I get that it means that neither R or P is favored since it is in the range of 10^-3 and 10^3. But why is that specific value rare? Might not be important but I'm curious


I think most others have brought up good, accurate points, but an interesting philosophical take on this is that k=1 isn't necessarily super rare, but rather that it is just as rare as most other equilibrium constants. However, since we (as a people) are interested and fixated on k=1 (as opposed to k=0.00000543 or k=5847873), since it is a base-10 number (and has the curious implication of equality in products and reactants), then it is worth noting that k=1 is rare. Arbitrarily, I could say that k=7 is rare, but that isn't interesting to people and so we don't focus on it.

However, I would like to reiterate that it is worth noting that the occurrence of exactly equal concentrations of products and reactants at equilibrium is said to be rare because of the intuitive contradiction that there would be anything equal between two very different sets (products and reactants) of compounds after chemical reaction.


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