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6E #1

Posted: Wed Jan 20, 2021 10:10 am
by marlene 1K
Calculate the pH of 0.15M H2SO4(aq) at 25C.
I'm a little confused on how to set this problem up especially in regards to the Ka and what the reaction itself would be for H2SO4 + H2O.

Re: 6E #1

Posted: Wed Jan 20, 2021 10:17 am
by Marisa Gaitan 2D
Since H2SO4 is a diprotic acid, it has two reactions that give off H3O+, the first: H2SO4 + H2O --> H3O+ + HSO4- and the second: HSO4- +H2O --> H3O+ + SO42-. Because H2SO4 is a strong acid, it dissociates completely. However, the second reaction needs an ICE table. Make sure to use the right concentration of H3O+ that results from the first reaction. Solve like a regular ICE table, using the Ka2 given and you can find the pH from there! Hope this helps.

Re: 6E #1

Posted: Wed Jan 20, 2021 10:24 am
by Kiran Singh 3A
I believe the reactions would be : (1) H2SO4 + H2O <--> HSO4(-) + H3O(+) (2) HSO4(-) + H2O <--> SO4(2-) + H3O(+). As for the Ka value, only the Ka2 (the Ka value for the second reaction) is needed to determine the concentration of hydronium and pH because the concentration calculated for the first reaction would be very similar, if not equal, to the initial concentration. Hope this helps!