I am confused by this statement:
"When pOH is less than pKb, the acid is deprotonated."
What does it mean for a base to be deprotonated?
Deprotonated bases
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Re: Deprotonated bases
For this I guess it helps to look at the base version of the H-H equation, pOH = pKb + log(BH+/B)
So if pOH < pKb then pOH - pKb is negative, so the equation becomes: -N = log(BH+/B), where -N is just some random negative number
then if you get rid of the log by doing 10^ to both sides you get 10^-N = BH+/B
But we know bc of power rules that that 10^-N is 1/(10^N) so the denominator is greater than the numerator, and using the equation that means that B is greater than BH+, since B is the deprotonated version this means when pOH < pKb there is more B (deprotonated) than BH+ (protonated)
So if pOH < pKb then pOH - pKb is negative, so the equation becomes: -N = log(BH+/B), where -N is just some random negative number
then if you get rid of the log by doing 10^ to both sides you get 10^-N = BH+/B
But we know bc of power rules that that 10^-N is 1/(10^N) so the denominator is greater than the numerator, and using the equation that means that B is greater than BH+, since B is the deprotonated version this means when pOH < pKb there is more B (deprotonated) than BH+ (protonated)
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Re: Deprotonated bases
The way I like to think of it is that for a strong base, for instance, deprotonation would imply that the base in its current state would likely resemble its conjugate acid. In the calculations for pkb values, deproponated would mean the concentration term of the "B" species that is not "BH".
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