The question is: The equilibrium constant, Kc, equals 0,045 at 250C for the decomposition reaction: PCl5 (g) <=> PCl3 (g) + Cl2 (g). Calculate the percentage of PCl5 that dissociates if 0.05 mole of PCl5 is placed in a closed vessel (constant volume) at 250C and 2.00 atm pressure.
In the solutions, the Kc=(x/1.072)^2/((0.05-x)/1.072)). Why don't we just find molarity by dividing 0.05 mol PCl5 with the volume we found and then put that into the ICE chart? Why do we have to divide all the concentrations at equilibrium with the volume in the Kc?
2012 Final #6B
Moderators: Chem_Mod, Chem_Admin
-
- Posts: 22
- Joined: Fri Sep 25, 2015 3:00 am
-
- Posts: 27
- Joined: Fri Sep 25, 2015 3:00 am
Re: 2012 Final #6B
Postby Suraj Palaparty 2F » Fri Dec 04, 2015 12:48 am
I believe that the volume was 1.072L, so that is essentially what they were doing. In the answers it was just all left in there in order to not break up the (0.05-x).
-
- Posts: 23
- Joined: Sat Jul 09, 2016 3:00 am
Re: 2012 Final #6B
Postby Fengting Liang 1F » Sat Dec 03, 2016 8:24 pm
Can someone explain how he goes from Kc=(x/1.072)^2/((0.05-x)/1.072)) and gets x=0.03059? I keep getting x=0.049 when I plug in Kc...
Return to “Equilibrium Constants & Calculating Concentrations”
Jump to
- NEWS
- NEWS & RESOURCES
- About The Forum
- Forum Rules and Helpful Hints
- How to make a New Post (submit a question) and use Equation Editor (click for details)
- Email Notification (click for details)
- How to Subscribe to a Forum, Subscribe to a Topic, and Bookmark a Topic (click for details)
- Endorsed Post (click for details)
- Multimedia Attachments (click for details)
- Strikethrough (click for details)
- Chem 14A
- Review of Chemical & Physical Principles
- SI Units, Unit Conversions
- Significant Figures
- Accuracy, Precision, Mole, Other Definitions
- Molarity, Solutions, Dilutions
- Empirical & Molecular Formulas
- Balancing Chemical Reactions
- Limiting Reactant Calculations
- The Quantum World
- Properties of Light
- Properties of Electrons
- Einstein Equation
- *Black Body Radiation
- Photoelectric Effect
- Bohr Frequency Condition, H-Atom , Atomic Spectroscopy
- DeBroglie Equation
- Heisenberg Indeterminacy (Uncertainty) Equation
- *Shrodinger Equation
- *Particle in a Box
- Wave Functions and s-, p-, d-, f- Orbitals
- Quantum Numbers and The H-Atom
- Electron Configurations for Multi-Electron Atoms
- Trends in The Periodic Table
- Chemical Bonds
- Ionic & Covalent Bonds
- Sigma & Pi Bonds
- Lewis Structures
- Resonance Structures
- Formal Charge and Oxidation Numbers
- Octet Exceptions
- Coordinate Covalent Bonds
- Polarisability of Anions, The Polarizing Power of Cations
- Electronegativity
- Dipole Moments
- Bond Lengths & Energies
- Forces and Liquid Structure
- Interionic and Intermolecular Forces (Ion-Ion, Ion-Dipole, Dipole-Dipole, Dipole-Induced Dipole, Dispersion/Induced Dipole-Induced Dipole/London Forces, Hydrogen Bonding)
- *Liquid Structure (Viscosity, Surface Tension, Liquid Crystals, Ionic Liquids)
- Molecular Shape and Structure
- Determining Molecular Shape (VSEPR)
- Hybridization
- *Molecular Orbital Theory (Bond Order, Diamagnetism, Paramagnetism)
- Coordination Compounds and their Biological Importance
- Naming
- Shape, Structure, Coordination Number, Ligands
- Biological Examples
- Industrial Examples
- *Stereochemistry
- *Crystal Field Theory
- *Molecular Orbital Theory Applied To Transition Metals
- Acids and Bases
- Properties & Structures of Inorganic & Organic Acids
- Properties & Structures of Inorganic & Organic Bases
- Amphoteric Compounds
- Lewis Acids & Bases
- Bronsted Acids & Bases
- Conjugate Acids & Bases
- Acidity & Basicity Constants and The Conjugate Seesaw
- Calculating pH or pOH for Strong & Weak Acids & Bases
- Polyprotic Acids & Bases
- Identifying Acidic & Basic Salts
- Calculating the pH of Salt Solutions
- Air Pollution & Acid Rain
- Chem 14A Uploaded Files (Worksheets, etc.)
- Student Social/Study Group
- Administrative Questions and Class Announcements
- General Science Questions
- *Aqueous Equilibria
- *Making Buffers & Calculating Buffer pH (Henderson-Hasselbalch Equation)
- *Biological Importance of Buffer Solutions
- *Titrations & Titration Calculations
- *Indicators
- Chem 14B
- Chemical Equilibrium
- Ideal Gases
- Equilibrium Constants & Calculating Concentrations
- Non-Equilibrium Conditions & The Reaction Quotient
- Applying Le Chatelier's Principle to Changes in Chemical & Physical Conditions
- Thermochemistry
- Phase Changes & Related Calculations
- Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
- Heat Capacities, Calorimeters & Calorimetry Calculations
- Thermodynamics
- Thermodynamic Systems (Open, Closed, Isolated)
- Thermodynamic Definitions (isochoric/isometric, isothermal, isobaric)
- Calculating Work of Expansion
- Concepts & Calculations Using First Law of Thermodynamics
- Concepts & Calculations Using Second Law of Thermodynamics
- Third Law of Thermodynamics (For a Unique Ground State (W=1): S -> 0 as T -> 0) and Calculations Using Boltzmann Equation for Entropy
- Entropy Changes Due to Changes in Volume and Temperature
- Calculating Standard Reaction Entropies (e.g. , Using Standard Molar Entropies)
- Gibbs Free Energy Concepts and Calculations
- Van't Hoff Equation
- Environment, Fossil Fuels, Alternative Fuels
- Biological Examples (*DNA Structural Transitions, etc.)
- Electrochemistry
- Balancing Redox Reactions
- Galvanic/Voltaic Cells, Calculating Standard Cell Potentials, Cell Diagrams
- Work, Gibbs Free Energy, Cell (Redox) Potentials
- Appications of the Nernst Equation (e.g., Concentration Cells, Non-Standard Cell Potentials, Calculating Equilibrium Constants and pH)
- Interesting Applications: Rechargeable Batteries (Cell Phones, Notebooks, Cars), Fuel Cells (Space Shuttle), Photovoltaic Cells (Solar Panels), Electrolysis, Rust
- Chemical Kinetics
- Kinetics vs. Thermodynamics Controlling a Reaction
- General Rate Laws
- Method of Initial Rates (To Determine n and k)
- Zero Order Reactions
- First Order Reactions
- Second Order Reactions
- Reaction Mechanisms, Reaction Profiles
- Arrhenius Equation, Activation Energies, Catalysts
- *Enzyme Kinetics
- Experimental Details
- Environment, Ozone, CFCs
- Biological Examples
- Chem 14B Uploaded Files (Worksheets, etc.)
- Student Social/Study Group
- Administrative Questions and Class Announcements
- General Science Questions
- *Thermodynamics and Kinetics of Organic Reactions
- *Electrophiles
- *Nucleophiles
- *Organic Reaction Mechanisms in General
- *Electrophilic Addition
- *Nucleophilic Substitution
- *Free Energy of Activation vs Activation Energy
- *Complex Reaction Coordinate Diagrams
- *Names and Structures of Organic Molecules
- *Alkanes
- *Cycloalkanes
- *Alkenes
- *Cycloalkenes
- *Alkynes
- *Constitutional and Geometric Isomers (cis, Z and trans, E)
- *Haloalkanes
- *Haloalkenes
- *Alcohols
- *Ethers
- *Aldehydes
- *Ketones
- *Carboxylic Acids
- *Amines
- *Identifying Primary, Secondary, Tertiary, Quaternary Carbons, Hydrogens, Nitrogens
- *Conformations of Organic Molecules
- *Alkanes and Substituted Alkanes (Staggered, Eclipsed, Gauche, Anti, Newman Projections)
- *Cyclopropanes and Cyclobutanes
- *Cyclopentanes
- *Cyclohexanes (Chair, Boat, Geometric Isomers)
- *Calculations Using ΔG° = -RT ln K
- *ChemDraw
- *Chem3D
- Chem 14C/D Topics
- Resonance in Organic Compounds
- Stereochemistry in Organic Compounds (Chirality, Stereoisomers, R/S, d/l, Fischer Projections)
Who is online
Users browsing this forum: No registered users and 8 guests