Equilibrium Composition

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donnanguyen1d
Posts: 64
Joined: Fri Sep 29, 2017 7:04 am

Equilibrium Composition

Postby donnanguyen1d » Thu Nov 23, 2017 5:50 pm

When calculating Equlibrium Composition when do we know to approximate or use the quadratic equation? And in approximation, what are we approximating?

Curtis Tam 1J
Posts: 105
Joined: Thu Jul 13, 2017 3:00 am

Re: Equilibrium Composition

Postby Curtis Tam 1J » Thu Nov 23, 2017 7:31 pm

I believe you approximate when you know the Kc value is really small, meaning any change "x" would be negligible, though it wouldn't be equal to zero. Is this what you are talking about?

Madelyn Gehrich 1E
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Re: Equilibrium Composition

Postby Madelyn Gehrich 1E » Thu Nov 23, 2017 9:44 pm

When the values of change in molar concentration and equilibrium in molar concentration are unknown (x), the answer you will get will be in terms of x. Thus, since this variable is unknown, we set it equal to 0 and use the quadratic equation to solve for x. If you have enough information from the problem, this won't be necessary if you aren't using variables in your problem solving.

Cassandra Mullen 1E
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Re: Equilibrium Composition

Postby Cassandra Mullen 1E » Thu Dec 07, 2017 10:30 pm

When you make x negligible under the small x assumption, you should check to make sure that you can use this assumption. To do this, calculate that the x value you get is less than 5% of the original concentration.

AnuPanneerselvam1H
Posts: 52
Joined: Fri Sep 29, 2017 7:07 am

Re: Equilibrium Composition

Postby AnuPanneerselvam1H » Fri Dec 08, 2017 2:44 am

When calculating the concentrations of products/reactants, we can approximate if the equilibrium constant is very small (<10^-5). This does not x is zero, but that x is very small and has a negligible effect.


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