introducing new gas to increase pressure

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Andrew Sun 3F
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Joined: Fri Sep 28, 2018 12:18 am

introducing new gas to increase pressure

Postby Andrew Sun 3F » Sat Jan 15, 2022 11:22 pm

I know that Dr. Lavelle said that introducing new gases doesn't shift equilibrium. However, how come it doesn't cause the reaction to shift towards the side with less moles? I think conceptually I am unsure.

Emaad Sohail 3F
Posts: 90
Joined: Fri Sep 24, 2021 5:13 am

Re: introducing new gas to increase pressure

Postby Emaad Sohail 3F » Sun Jan 16, 2022 12:25 am

While I'm not entirely sure myself, I think it's because adding another gas doesn't affect the concentration if the volume is kept constant- you still have the same number of moles in the same space, so the concentration stays the same. This means the K equation doesn't change since the concentrations are still the same.

Molly McAndrew 1 1H
Posts: 103
Joined: Fri Sep 24, 2021 5:08 am

Re: introducing new gas to increase pressure

Postby Molly McAndrew 1 1H » Sun Jan 16, 2022 8:10 am

Increasing pressure can change the concentration of reactants or products and cause the reaction to shift one way or the other. However, the reaction will return to equilibrium following this shift and the equilibrium constant (i.e. ratio of products/reactants) will remain the same. Dr. Lavelle emphasizes that while the concentration of gases can change and likely will, a change in pressure will not change the equilibrium constant.


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