Why is HF not classified as a strong acid?
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Why is HF not classified as a strong acid?
The general trend of the hydrohalic acids (HCl, HBr, HI) is that HCl is stronger than HBr and HI is stronger than HBr. These 3 acids are all classified as strong as well. Why is HF not classified as a strong acid? What property of HF causes it to not completely dissociate in solution(be classified as a weak acid)?
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Re: Why is HF not classified as a strong acid?
Since F is so electronegative, it holds on tightly to the H (stronger and shorter bond) making it hard to dissociate.
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Re: Why is HF not classified as a strong acid?
HF initially almost completely disassociates, but after, it participates in other reactions with itself and with water, essentially unassociating the acid and then behaving like a weak acid
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Re: Why is HF not classified as a strong acid?
I believe that HF is considered a weak acid since it doesn't lose the H+ easily. This is due to F's electronegativity and the fact that the bond between H and F is short since F has a small atomic radius. Because the bond is short, the bond is stronger, and it is harder for the HF to lose its H+, making it a weak acid.
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Re: Why is HF not classified as a strong acid?
Strong acids are characterized by their ability to dissociate completely into H+ ions. HF has an extremely short bond because of its small atomic radius (thus the nucleus of Fluorine has a greater pulling power), as well as it's high electronegativity. Because of HF's properties, HF is unable to completely dissociate into its constituent H+ and F- ions, and is thus a weak acid.
Hope this helps!
Andre
Hope this helps!
Andre
Re: Why is HF not classified as a strong acid?
As others have mentioned, it is extremely hard for HF to dissociated into its constitutive ions as it is the smallest atom out of all the others. Since how easily a bond dissociates is a measure of how strong an acid is, with easier dissociations equating to stronger acids, HF is not considered a strong acid.
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Re: Why is HF not classified as a strong acid?
Strong acids are classified by the degree of dissociation in solution. HF not only has a short bond (which makes it harder to dissociate) it also has an F- (which has high electronegativity). Therefore, HF is unable to completely dissociate into H+ and F- making it a weak acid.
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Re: Why is HF not classified as a strong acid?
Hi! The bond length between H and F is shorter than the other bonds mentioned, and additionally, F is very electronegative so it is difficult for it to completely dissociate. Strong acids are easily dissociable, due to their longer and weaker bonds and closer electronegativity differences (in this example).
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Re: Why is HF not classified as a strong acid?
In the textbook, it mentions that for binary acids especially, as you go down a group, the acid becomes stronger, since the bond enthalpy is lower. Thus, since F is at the top of the fluorine group, it's forms the weakest acid with H. All elements above Br form weak binary acids with hydrogen.
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Re: Why is HF not classified as a strong acid?
Fluorine is extremely electronegative, so it's much harder for it to dissociate. This means it's considered a weak acid, because acid strength is determined by their ability to dissociate in water.
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Re: Why is HF not classified as a strong acid?
The H-F bond is short and strong, which makes HF harder to give out protons. Thus weak acid.
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Re: Why is HF not classified as a strong acid?
Strong acids are characterized by their ability to dissociate completely into H+ ions. F is so electronegative with a short bond length to the Hydrogen so it will not want to fully dissociate that easily.
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Re: Why is HF not classified as a strong acid?
Since F is very electronegative, it is much harder for HF to dissociate into H+ ions, making it a weak acid.
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Re: Why is HF not classified as a strong acid?
HF cannot be classified as a strong acid because fluorine has the highest electronegativity on the periodic table of element so it holds onto that hydrogen very tightly making it not a strong acid, but do not forget it is still an acid.
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Re: Why is HF not classified as a strong acid?
My guess is that since fluorine is so electronegative, it doesn't let go of the electron as easily as other halogens might. This would make it harder for HF to dissociate in water, and so weaken the acid, thus making it not a strong acid.
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Re: Why is HF not classified as a strong acid?
HF is not a strong acid as F is so electronegative, which means that HF does not easily dissociate into H+ and F- easily in water. This is why, as atomic radius increases, the acids become stronger as they are able to dissociate much easier.
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Re: Why is HF not classified as a strong acid?
HF is not classified as a strong acid because its ability to dissociate to donate proton is low.
Re: Why is HF not classified as a strong acid?
It is not classified as a strong acid due to how the strength of the H-F bond. Since it is stronger than the rest of the halogens, it does not break as easily therefore it does not dissociate nearly as much as the strong acids.
Re: Why is HF not classified as a strong acid?
I am not sure if this was already mentioned, but the bond length of HF is pretty short, so it makes it harder to break that bond. Shorter bonds = stronger bonds = weaker acids.
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Re: Why is HF not classified as a strong acid?
Fluorine is so electronegative that it holds onto its electrons, so it will not let go of that hydrogen easily. Strong acids are those that will give up the hydrogen easily, so HF is not a strong acid.
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