NH3 as a weak base

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Gabriel Wolf 3I
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Joined: Fri Sep 24, 2021 5:22 am

NH3 as a weak base

Postby Gabriel Wolf 3I » Wed Jan 12, 2022 2:48 pm

Why does NH3 act as a weak base when it has a higher ionization energy than oxygen? Wouldn't the Nitrogen hold onto the electron pair more than the oxygen, meaning the Hydrogen would have less access to electrons if it bound to NH3? Wouldn't this be less favorable than the reactions that occur between hydrogen and oxygen in pure water?

Fiona H 2E
Posts: 106
Joined: Fri Sep 24, 2021 5:26 am

Re: NH3 as a weak base

Postby Fiona H 2E » Wed Jan 12, 2022 5:00 pm

Ammonia doesn't contain any hydroxide ions to begin with, but when it's dissolved in water it acquires hydrogen ions from the water to produce hydroxide as well as ammonium ions. However, ammonia doesn't fully convert into hydroxide and ammonium ions in a solution, which is why it is considered a weak base.

HemangD 3K
Posts: 51
Joined: Mon Jan 03, 2022 9:38 pm

Re: NH3 as a weak base

Postby HemangD 3K » Sun Jan 16, 2022 11:55 am

You are right about how it's harder to take an electron away from nitrogen than to take an electron away from oxygen. However, I don't think this information plays a role in categorizing bases as weak or strong. From my understanding, a base is categorized as weak or strong depending on how much of it is able to dissociate in solution. Since ammonia only partially dissociates, it is categorized as a weak base. If it fully dissociated, then it would be categorized as a strong base.

005502505
Posts: 49
Joined: Wed Feb 17, 2021 12:17 am

Re: NH3 as a weak base

Postby 005502505 » Sun Jan 16, 2022 4:38 pm

When dissolved in water, ammonia acquires hydrogen ions from the water in order to make hydroxide. It doesn't fully convert these ions, however, leading to its categorization as a weak base. Hope this helps!!


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