stronger acid ?

Moderators: Chem_Mod, Chem_Admin

Christineg1G
Posts: 115
Joined: Fri Aug 09, 2019 12:15 am
Been upvoted: 1 time

stronger acid ?

Postby Christineg1G » Mon Dec 02, 2019 9:34 pm

why is HClO2 stronger than HBrO2 ?

JohannaPerezH2F
Posts: 94
Joined: Wed Sep 18, 2019 12:18 am

Re: stronger acid ?

Postby JohannaPerezH2F » Mon Dec 02, 2019 9:39 pm

In both acid the oxidation number of chlorine and bromine are same ,that is +3 . But chlorine atom is more electronegative than bromine atom . So the electron of O - H bond strongly attract Cl atom towards itself than bromine atom . ... Consequently , HClO2 is more stroger acid than HBrO2

Nawal Dandachi 1G
Posts: 102
Joined: Sat Sep 28, 2019 12:16 am

Re: stronger acid ?

Postby Nawal Dandachi 1G » Mon Dec 02, 2019 9:39 pm

HClO2 is a stronger acid than HBrO2 because Cl has a higher electronegativity than Br.

Jessica Tejero 3L
Posts: 54
Joined: Wed Sep 25, 2019 12:16 am

Re: stronger acid ?

Postby Jessica Tejero 3L » Mon Dec 02, 2019 10:10 pm

Usually the stronger acid is the element with the higher electronegativity.

eve444
Posts: 104
Joined: Fri Sep 24, 2021 6:41 am

Re: stronger acid ?

Postby eve444 » Fri Dec 03, 2021 2:02 am

with oxyacids (when everything else is the same except 1 atom), usually, you want to look at electronegativity. this is because the higher the electronegativity is, the more the electrons will be pulled towards that atom, making the resulting acid stronger (H atom is easier to pull off). So in this case, HClO2 would be stronger than HBrO2

Ginny Ghang 1B
Posts: 102
Joined: Fri Sep 24, 2021 7:22 am

Re: stronger acid ?

Postby Ginny Ghang 1B » Fri Dec 03, 2021 11:33 am

Since they have the same number of oxygens, you look at the electronegativity of the halogen. The greater the electronegativity of the halogen, the stronger the oxoacid. This is because the electrons are withdrawn slightly from O - H as the element gets more electronegative, making the O - H more polar. This makes the molecule a stronger acid. So HClO2 is stronger.

Mark_Botros_1D
Posts: 111
Joined: Fri Sep 24, 2021 5:12 am

Re: stronger acid ?

Postby Mark_Botros_1D » Fri Dec 03, 2021 11:44 am

Furthermore, to add to the discussion, we are considering electronegativity and not bond length because the hydrogen is bound to the oxygen atom in both acids.

Evan L 2B
Posts: 101
Joined: Fri Sep 24, 2021 6:20 am

Re: stronger acid ?

Postby Evan L 2B » Fri Dec 03, 2021 12:10 pm

Cl is more electronegative than Br which means that it allows the h+ ion in the molecule to be lost more easily and therefore make the molecule a stronger acid

emily3L
Posts: 114
Joined: Fri Sep 24, 2021 7:20 am

Re: stronger acid ?

Postby emily3L » Fri Dec 03, 2021 12:27 pm

HClO2 is a stronger acid than HBrO2 because Cl is more electronegative than Br because the chlorines pull electron density away from both oxygens, which stabilizes /delocalizes the negative charge.


Return to “Bronsted Acids & Bases”

Who is online

Users browsing this forum: No registered users and 5 guests